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  • Lissajous diagrams  (1)
  • diffusion  (1)
  • 1
    ISSN: 1572-882X
    Schlagwort(e): cellulose ; magnetic resonance imaging ; diffusion ; structure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Abstract NMR imaging and spatially resolved diffusometry have been used to study the distribution of water within swollen cellophane and measure its diffusion coefficient. Water concentration and diffusion coefficient were found to be essentially constant across most of the film thickness. However, significantly slower diffusion was indicated for water near the film surface (D = 0.5 × 10−9 m2 s−1) compared with water in the centre of the film (D = 0.88 × 10−9 m2 s−1). This was also reflected in lower T 2 values at the edge of the film indicating water with more restricted motion. These observations were interpreted in terms of dense surface regions of cellulose (skin) over a more porous interior (core).
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of thermal analysis and calorimetry 56 (1999), S. 1011-1016 
    ISSN: 1572-8943
    Schlagwort(e): crystallisation ; glass transition ; Lissajous diagrams ; modulated temperature power compensation differential scanning calorimetry ; polyethylene terephthalate/polycarbonate blends
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A modulated temperature power compensated differential scanning calorimeter, MTDSC, has been built from a standard Perkin-Elmer DSC model-2 such that a computer generated voltage has been applied to induce a sinusoidal change in sample temperature superimposed on a linear heating rate. The effect of amplitude of the temperature fluctuation, modulation period and block temperature on the reversibility has been assessed from the Lissajous diagram of heat flow vs. sample temperature. From their reproducibility and symmetry the most effective conditions for operating the MTDSC has been deduced. The specific heat of sapphire has been measured using these operational conditions for comparison with conventional DSC. Phase separated blends of polycarbonate (PC) and polyethylene terephthalate (PET) have been analysed.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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