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Conductance and ion association in dimethylsulfite (1986)

Plichta, E. ; Salomon, M. ; Slane, S. ; [et al.]

Springer

Journal of solution chemistry 15 (1986), S. 663-673

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ISSN: 1572-8927

Keywords: Conductivities ; Ion association ; 1∶1 electrolytes ; acetone ; dimethylsulfite

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The electrolytic conductances of LiClO4, LiAsF6, NaClO4 and the n-butylammonium salts Bu4NCl, Bu4NClO4, and Bu4NBPh4 (tetraphenylborate) have been determined in dimethylsufite at 25°C. Ion association constants calculated from these data are interpreted in terms of solvent-separated ion pairs (for LiClO4, LiAsF6, and NaClO4), and contact ion pairs (for the n-butyl-ammonium salts). Comparisons are made for analogous electrolytes in acetone, and in which all salts form contact ion pairs.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00644598

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