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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 14 (1985), S. 473-484 
    ISSN: 1572-8927
    Keywords: Lanthanide nitrates ; hydrates ; solubilities ; activities ; solvation energies ; phase transitions ; congruent melting points ; specific solvation ; metastable equilibria ; tetrad effect ; double-double effect
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The thermodynamic properties of saturated aqueous lanthanide nitrate solutions were determined using recently published critically evaluated solubility and activity data. The variation of the thermodynamic functions and congruent melting points as a function of atomic number are interpreted in terms of changes in inner sphere coordination number in both the solid hexahydrates and in the aquo ions, and in terms of the double-double effect. Inconsistencies in experimental solubility data are generally caused by uncertainties in solid phase composition which is shown to be due to the very small Gibbs energies accompanying transitions from stable to metastable systems differing in the number of hydrating water molecules.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-601X
    Keywords: 25.70.Np
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We report a preliminary measurement of coincident neutron-proton pairs emitted at 45° in the interaction of 400, 530, and 650 MeV/A neon beams incident on uranium. Charged particles were identified by time of flight and momentum, as determined in a magnetic spectrometer. Neutral particles were detected using a thick plastic scintillator, and their time of flight was measured between an entrance scintillator, triggered by a charged particle, and the neutron detector. The scatter plots and contour plots of neutron momentum vs. proton momentum appear to show a slight correlation ridge above an uncorrelated background. The projections of this plane on then-p momentum difference axis are essentially flat, showing a one standard deviation enhancement for each of the three beams energies. At each beam energy, the calculated momentum correlation function for the neutron-proton pairs is enhanced near zero neutron-proton momentum difference by approximately one standard deviation over the expected value for no correlation. This enhancement is expected to occur as a consequence of the attractive final state interaction between the neutron and proton (i.e., virtual or “singlet” deuterons). The implications of these measurements are discussed.
    Type of Medium: Electronic Resource
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