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  • Artikel: DFG Deutsche Nationallizenzen  (2)
  • glass microfiber  (1)
  • hydrolysis/condensation  (1)
Datenquelle
  • Artikel: DFG Deutsche Nationallizenzen  (2)
Materialart
Erscheinungszeitraum
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of nanoparticle research 1 (1999), S. 379-392 
    ISSN: 1572-896X
    Schlagwort(e): nanoparticles ; aero-sol-gel ; aerosol ; sol-gel ; hydrolysis/condensation ; silica
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik , Technik allgemein
    Notizen: Abstract This paper discusses a new approach to the synthesis of nano-structured oxides where sol-gel reactions are carried out in aerosol droplets. This aero-sol-gel (ASG) reactor allows for manipulation of the structure, chemical composition and surface area of silica powders through variation of process parameters. ASG powders differ in nanostructure from other continuous process powders such as pyrolytic and solution-route powders. ASG powders contain mesopores (〉2-nm) and micropores (〈2-nm), the mesopores being responsible for high surface areas measured by nitrogen adsorption using BET theory. Primary particles of close to molecular scale are believed to lead to exceedingly large specific surface areas on the order of 600-m2/g. These primary particles aggregate into nanometer scale mass-fractal aggregates that cluster in micron scale agglomerates. Under controlled reaction conditions the powder structure is reproducible as measured by small-angle X-ray scattering, SAXS, analysis. The ASG reactor displays transport effects similar to those previously seen in laminar flame reactors as evidenced by the effect of reactor geometry and reactant concentration on product structure.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 3147-3154 
    ISSN: 0887-6266
    Schlagwort(e): glass microfiber ; scattering ; polymer ; nonwoven fabrics ; polymer analogue ; Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Disordered fiber mats made of glass microfibers (GMF) were studied using small-angle light scattering (SALS), ultrasmall-angle X-ray scattering (USAXS), SEM, and optical microscopy. The morphological scaling of these materials in the micron scale was very similar to that of polymers in the nanometer scale. In some fiber mats, such as GMF, the structure is randomized at the time of formation, leading to a statistical analogy with the thermal randomization that occurs in nanometer-scale, high polymers. Analogues for the coil radius-of-gyration, persistence unit, and scaling regimes exist in such fiber mats and may be a useful feature both for modeling thermally equilibrated polymeric systems, as well as furthering the understanding of the physical properties of fiber mats through analogy with the theoretical understanding of thermally equilibrated polymeric systems. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 3147-3154, 1998
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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