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  • Articles: DFG German National Licenses  (2)
  • integrated assessment  (1)
  • model  (1)
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  • Articles: DFG German National Licenses  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 91 (1996), S. 271-282 
    ISSN: 1573-2932
    Keywords: acidification ; diatom ; model ; organic acids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We employed three mathematical models to make quantitative estimates of the pH of 33 statistically-selected lakes in the Adirondack mountains, New York (USA) prior to the Industrial Revolution (1840). The models included 1) the MAGIC watershed acidification model, 2) a paleolimnological model of diatom-inferred pH, and 3) the MAGIC model modified to incorporate an empirically-based model of natural organic acidity. Application of approaches 2) and 3) yielded consistent estimates of pre-industrial Adirondack lakewater pH. However, when the organic acid model was not included, MAGIC calculations and diatom-inferred values showed poor agreement. MAGIC projections of lakewater pH 50 years into the future, under differing atmospheric deposition scenarios, were also sensitive to inclusion of the organic acid model. MAGIC predicted greater recovery in response to reduced deposition when organic acids were not considered. These results suggest that failure to consider the pH buffering of naturally-occurring organic acidity will often result in biased projections which overemphasize the response of lakewater pH to changes in atmospheric inputs of strong acid.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-2932
    Keywords: acid deposition ; Adirondacks ; integrated assessment ; lake acidification ; mathematical model ; reduced-form modelling ; soil acidification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A reduced-from modelling approach is used to predict soil and lake acidification as part of an integrated assessment of acid deposition effects and control strategies. The reduced-form model is based upon the mechanistic, lumped parameter watershed chemistry model, MAGIC (Model of Acidification of Groundwater in Catchments). Recent improvements to MAGIC are described, and its reduced-form representation in the Tracking and Analysis Framework (TAF), an integrated assessment model for decision and uncertainty analysis, is presented. Reduced-form models are developed for lake acid neutralising capacity (ANC), calcium, pH, and aluminium; and for soil base saturation. The model for lake ANC incorporates long-term depletion of the watershed acid neutralisation fraction, as is predicted to occur with MAGIC. In test calibrations for 33 representative watersheds in the Adirondacks, the resulting reduced-form model provides a close approximation to MAGIC, with average root mean square errors of 0.79 μeq l-1 for ANC, 1.09 μeq l-1 for calcium, 0.16 for pH, 2.52 μeq l-1 for aluminium, and 0.09% for soil base saturation. In addition, improved fish viability models are incorporated in the integrated assessment model, and predictions are demonstrated for a future deposition reduction scenario for the Adirondack region.
    Type of Medium: Electronic Resource
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