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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 19 (1990), S. 437-446 
    ISSN: 1572-8927
    Keywords: Acetone ; enthalpy of crystallization ; enthalpy of dissolution ; enthalpy of transition ; ion-solvent interaction ; lithium chloride ; methanol ; N,N-dimethylformamide ; solvation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The crystallization enthalpy of LiCl at 25°C in LiCl-H2O-cosolvent systems is determined calorimetrically as a function of the cosolvent content in the mixed solvent. This parameter is used for the investigation of heat phenomena accompanying the solvation of the salt in a saturated solution. The cosolvents employed include methanol, acetone, and N,N-dimethylformamide. The most pronounced change is effected by replacement of water with N,N-dimethylformamide.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 12 (1983), S. 855-860 
    ISSN: 1572-8927
    Keywords: Calorimetry ; mixing enthalpy ; concentrated aqueous solutions ; zinc chloride ; lithium chloride ; hydrated melts ; complex formation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Measurements of the enthalpy of mixing at 25°C for the hydrate system (ZnCl2+RH2O)−(LiCl+RH2O) are reported. A distinct maximum and a pronounced shoulder appears in the enthalpy of mixing data at mole fractions of XZnCl2=0.33 and 0.50, respectively, forR equal to about 4.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 15 (1986), S. 269-282 
    ISSN: 1572-8927
    Keywords: Activity coefficients ; enthalpy of crystallization ; enthalpy of dissolution ; enthalpy of formation ; lithium chloride ; solubility
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The enthalpies of crystallization of LiCl and LiCl·H2O from aqueous solutions at 25°C are reported as measured by a calorimetric method and derived from the previously published concentration dependence of the enthalpy of solution data. The results are compared with those obtained from the concentration dependence of activity coefficients and from the temperature dependence of solubilities.
    Type of Medium: Electronic Resource
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