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  • 1990-1994  (3)
  • methanol synthesis  (2)
  • Chemistry  (1)
  • 1
    ISSN: 1572-879X
    Schlagwort(e): methanol synthesis ; copper catalyst ; oxygen coverage
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The coverage of oxygen formed on the surface of catalysts during methanol synthesis from CO2 has been measured for copper-based catalysts including various metal oxides using a method called reactive frontal chromatography (RFC). An excellent correlation between the specific activity for methanol synthesis and the oxygen coverage (θ) was obtained, where the activity increased linearly with oxygen coverage atθ〈0.16 and then decreased atθ〉0.18. The results strongly indicate that the support effect or addition of metal oxides revealed in methanol synthesis over copper catalysts is ascribed to the ratio of Cu+ to Cu0 on the surface of copper particles.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Catalysis letters 27 (1994), S. 67-78 
    ISSN: 1572-879X
    Schlagwort(e): methanol synthesis ; Cu/ZnO catalyst ; Cu-Zn alloy ; effect of reduction temperature
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The behavior and role of ZnO in Cu/ZnO catalysts for the hydrogenations of CO and CO2 were studied using XRD, TEM coupled with EDX, TPD and FT-IR. As the reduction temperature increased, the specific activity for the hydrogenation of CO2 increased, whereas the activity for the hydrogenation of CO decreased. The EDX and XRD results definitely showed that ZnO x (x = 0–1) moieties migrate onto the Cu surface and dissolve into the Cu particle forming a Cu-Zn alloy when the Cu/ZnO catalysts were reduced at high temperatures above 600 K. The content of Zn dissolved in the Cu particles increased with reduction temperature and reached ∼ 18% at a reduction temperature of 723 K. The CO-TPD and FT-IR results suggested the presence of Cu+ sites formed in the vicinity of ZnO x on the Cu surface, where the Cu+ species were regarded as an active catalytic component for methanol synthesis.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 43 (1991), S. 767-773 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Based on the Mueller matrix approach, we have successfully designed and constructed a highly sensitive instrument for measuring optical birefringence (LB) by using a polarization modulation method and phase-sensitive technique. Our instrument can measure the retardation of a sample up to 10-2 radian. Using this instrument, we have measured the residual birefringence of thermosetting resins, CR-39 resin and epoxy resin, for opticaldisk substrates. CR-39 resin results are summarized as follows: (1) Annealing is very effective in reducing LB of samples; (2) samples prepared from raw material 2 (monomer purity, 96%, oligomer, 4%) have smaller LB than those from raw material 1 (monomer purity, 99.9%); and (3) annealed samples prepared from 2 satisfy the requirement on LB to be used as optical-disk substrates. For epoxy resin: (1) “Second curing” largely reduces LB of samples; (2) “slow cooling” is more effective in reducing LB of samples than “fast cooling;” (3) after the second curing, cutting does not induce any residual stress birefringence in samples; and (4) slow-cooled samples have good optical properties to be used as optical disk substrates.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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