ISSN:
1572-879X
Keywords:
Oxygen isotope exchange
;
Pt electrode
;
solid oxide electrolyte
;
oxygen pumping
;
NEMCA phenomena
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Homomolecular oxygen exchange on Pt electrode in a zirconia electrochemical cell was studied. It was found that the current passing through the cell (O2− pumping through the electrolyte) does not change the rate of oxygen exchange on the Pt electrode with respect to its open circuit value, a fact that indicates that the strength of the chemisorptive bond of oxygen on the Pt electrode is invariant under open and closed circuit conditions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00769508
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