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  • 1
    ISSN: 1573-1561
    Schlagwort(e): sex pheromone ; tergal gland ; Lutzomyia longipalpis ; Diptera ; Psychodidae ; gas chromatography ; high-pressure liquid chromatography
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract The sex pheromone component of maleLutzomyia longipalpis tergal gland extract was isolated and its activity confirmed by bioassay. Whole tergal gland extract was analyzed by HPLC and fractions were collected as they eluted from the detector. Each fraction was tested in an attraction bioassay with virgin unfed femaleLutzomyia longipalpis. HPLC analysis showed that whole extract contained several peaks; one large peak, one small peak and several minor peaks. Purity of the HPLC fractions was determined by GC analysis. The bioassays revealed that the large peak was responsible for most of the observed female behavior. The addition of the small peak to the large peak improved the response although by itself the small peak failed to elicit any significant behavior. Minor peaks failed to elicit any response. Chemical analysis revealed the large peak to be a relatively nonpolar hydrocarbon.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    ISSN: 1573-1561
    Schlagwort(e): Sex pheromone ; tergal gland ; Lutzomyia longipalpis ; gas chromatography ; mass spectrometry ; high-performance liquid chromatography ; nuclear magnetic resonance ; homosesquiterpene ; 9-methylgermacrene-B
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract The principal volatile component (99 + %) of the sex pheromone glands ofLutzomyia longipalpis from Lapinha, Brazil, has been isolated and characterized as a novel homosesquiterpene with the specific structure proposed as 9-methylgermacrene-B, (E,E)-8-(1-methylethylidenyl)-1,5,10-trimethyl-1,5-cyclodecadiene.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    ISSN: 1573-1561
    Schlagwort(e): Sex pheromone ; tergal gland ; Lutzomyia longipalpis ; 3-methyl-α-himachalene ; homosesquiterpene ; mass spectrometry ; high-performance liquid chromatography ; nuclear magnetic resonance
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract The principal behaviorally active volatile component (ca. 90% +) of the sex pheromone glands ofLutzomyia longipalpis from Jacobina. Brazil, has been isolated and characterized as a novel homosesquiterpene with the structure 3-methyl-α-himachalene (C16H26). A minor component (ca. 10%) of the gland extract has also been identified as the sesquiterpeneα-himachalene (C15H24). This work confirms that there are at least 3 members of theL. longipalpis species complex.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    ISSN: 1573-1561
    Schlagwort(e): Scent gland ; defensive secretion ; Hotea gambiae ; Heteroptera ; Scutelleridae ; (E)-2-hexenol ; hex-2-enal ; oct-2-enal ; 4-oxohex-2-enal ; β-pinene ; limonene ; sex dimorphism ; feeding ; repellent ; pheromone ; ovicide ; Calliphora ; Diptera ; Calliphoridae
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract The occurrence inHotea gambia adults of a sexual dimorphism in the divided dorsal abdominal scent gland (dg 1)is reported. Counts made of ducted secretory units indicate that female dg 1 regresses at the end of larval development, unlike male dg 1 which undergoes no regression. Other dorsal abdominal scent glands (dg 2, dg 3) which function in the larvae cease to function during the imaginai moult. From gas chromatographic, mass spectrometric and [1H]NMR data, the identity of the secretion from male adult dg 1 was established as virtually pure (E)-2-hexenol (a 100-mg mature male adult contains 0.5–1 μl of secretion). 2-Hexenol was also found in the reduced female adult dg 1. In the sexually monomorphic metathoracic scent gland, (E)-2-alkenals (C6, C8) and (E)-4-oxohex-2-enal, together with monoterpenes (β-pinene, limonene) but not 2-hexenol, were identified. The vapor of (E)-2-hexenol is repellent to both sexes ofHotea adults and toxic to blowfly (Calliphora) eggs.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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