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  • 1
    Digitale Medien
    Digitale Medien
    Novel Solid-State Synthesis of Polyfunctionalized 3,9-Diazatetraasteranes (1998)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 1213-1218 
    Details
    ISSN: 1434-193X
    Schlagwort(e): Cycloadditions ; Diazatetraasteranes ; Crystal structure ; Solid-state chemistry ; Photochemistry ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Upon irradiation, crystalline 4-methoxyphenyl-1,4-dihy-dropyridines 1 undergo nearly quantitative [2+2]cyclo-addition to form, via the ring-open intermediates 2, the centrosymmetric, polyfunctionalized 3,9-diazatetraasteranes 3. The centrosymmetric character of 3 was confirmed by 1H NMR spectral data as well as by X-ray crystal structure analysis. The dimerization reactions prove to be topochemically controlled by the nearest distance between potentially reacting double bonds, as well as by the conformationally determined packing restraints. This latter factor is shown by the X-ray crystal structure analysis of one dimerizing and one photostable derivative of the monomers 1.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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    Artikel (Nationallizenzen)
  • 2
    Digitale Medien
    Digitale Medien
    Solution-Dimerization of 4-Aryl-1,4-dihydropyridines (2000)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 245-249 
    Details
    ISSN: 1434-193X
    Schlagwort(e): Cycloadditions ; Cage compounds ; Dimerizations ; Steric hindrance ; Photochemistry ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: ---On irradiation at λ ≥ 270 nm solutions of 4-aryl-1,4-dihydropyridines 1 yield cage dimers 2 as the main products beside small amounts of anti dimers 3. 1H-NMR data and X-ray crystal structure prove centrosymmetrical properties for both dimers with axially orientated 4-aryl substituents. Irradiation with filtered light (λ 〉 313 nm) leads to syn and anti dimers 4 and 3 in nearly equal yields. The poor yields of anti dimers 3 on irradiation with unfiltered light are demonstrated to result from a partial cleavage back to their monomeric starting materials 1.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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    Artikel (Nationallizenzen)
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