ISSN:
1573-1111
Keywords:
Intercalation
;
α-tin(IV) hydrogen phosphate
;
α-vanadyl phosphate
;
ferrocene
;
dimethylaminomethylferrocene
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The intercalation of ferrocene and dimethylaminomethylferrocene into α-tin(IV) hydrogen phosphate (SnP) and α-vanadyl phosphate has been investigated. Successful intercalation of 0.81 mol of dimethylamino-methylferrocene into α-SnP by an acid-base reaction in aqueous medium to form a bilayer of protonated amines was achieved. However, ferrocene was not intercalated under the same conditions. Intercalation of α-vanadyl phosphate by 0.11 mol of ferrocene in acetonic medium at room temperature was effected by a redox topotactic reaction. The voluminous dimethylaminomethylferrocene was not intercalated into α-vanadyl phosphate.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00665366
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