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Photochemistry of matrix-isolated norbornadiene (1989)

Gȩbicki, Jerzy ; Kuberski, Sławomir ; Kamiński, Rafał

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 2 (1989), S. 383-388

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Details

ISSN: 0894-3230

Schlagwort(e): Organic Chemistry ; Physical Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: Norbornadiene, isolated in argon, xenon and nitrogen matrices at 20 K, was irradiated with UV light. Characterized by UV-VIS-IR absorption spectroscopy the photoproduct, representing a single species, was assigned to quadricyclane. This result is compared with the literature data on photochemistry of norbornadiene in the gas and liquid phase. The role of the rigid matrix environment on selectivity of the photochemical reaction is discussed.

Zusätzliches Material: 3 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/poc.610020504

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