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  • 1
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 751-764 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: This paper describes reactive flow in permeable media based on a numerical model that assumes local thermodynamic equilibrium. The model simulates single-phase, one-dimensional flow with greater generality than any model in the current literature. The mathematical foundation for the formulation is discussed in some detail. Results for hypothetical examples demonstrate that ion exchange and precipitation/dissolution of solids can interact to produce wave behavior not possible with either phenomenon alone. An important application involving both ion exchange and precipitation/dissolution is alkaline flooding. Model predictions for several laboratory alkaline floods indicate that the assumption of equilibrium is justified for these experiments. Simple calculations based on the equilibrium theory provide estimates of pH loss and hydroxide penetration distance.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1271-1287 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A theory for flow through permeable media with equilibrium precipitation/dissolution interactions is rigorously established. The general solution in terms of waves, which represent the propagation of concentration changes is developed, and the detailed structure of a precipitation/dissolution wave in the presence of dissipation (diffusion and dispersion) is derived; this structure plays a vital role in the general solution. The solution is based on Riemann invariants and thus exhibits certain similarities to wave solutions of related problems in gas dynamics and chromatography. However, a discontinuity peculiar to the precipitation/dissolution problem prevents unification of these similar solutions into a single, more general theory.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 317-328 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A model is developed that calculates the chemical equilibrium that exists between a flowing electrolyte solution and mineral assemblages. The development computes the mineral and aqueous compositions as a function of time and position in a one-dimensional porous medium. The model considers the dissolution of solids as well as their precipitation. The application of the model to various problems has revealed that characteristic aqueous and solid phase concentration waves develop and propagate through the system in a chromatographic manner. Example calculations are presented that illustrate the widespread applicability of the model. Specifically, a calculation is presented that reproduces the genetic mineralization features that are found in sandstone-type uranium deposits.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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