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  • 1
    Electronic Resource
    Electronic Resource
    Interactions of precipitation/dissolution waves and ion exchange in flow through permeable media (1986)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 32 (1986), S. 751-764 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes reactive flow in permeable media based on a numerical model that assumes local thermodynamic equilibrium. The model simulates single-phase, one-dimensional flow with greater generality than any model in the current literature. The mathematical foundation for the formulation is discussed in some detail. Results for hypothetical examples demonstrate that ion exchange and precipitation/dissolution of solids can interact to produce wave behavior not possible with either phenomenon alone. An important application involving both ion exchange and precipitation/dissolution is alkaline flooding. Model predictions for several laboratory alkaline floods indicate that the assumption of equilibrium is justified for these experiments. Simple calculations based on the equilibrium theory provide estimates of pH loss and hydroxide penetration distance.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690320505
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Precipitation and dissolution of solids attending flow through porous media (1984)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 317-328 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is developed that calculates the chemical equilibrium that exists between a flowing electrolyte solution and mineral assemblages. The development computes the mineral and aqueous compositions as a function of time and position in a one-dimensional porous medium. The model considers the dissolution of solids as well as their precipitation. The application of the model to various problems has revealed that characteristic aqueous and solid phase concentration waves develop and propagate through the system in a chromatographic manner. Example calculations are presented that illustrate the widespread applicability of the model. Specifically, a calculation is presented that reproduces the genetic mineralization features that are found in sandstone-type uranium deposits.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690300222
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    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Mineral sequences in precipitation/dissolution waves (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1271-1287 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theory for flow through permeable media with equilibrium precipitation/dissolution interactions is rigorously established. The general solution in terms of waves, which represent the propagation of concentration changes is developed, and the detailed structure of a precipitation/dissolution wave in the presence of dissipation (diffusion and dispersion) is derived; this structure plays a vital role in the general solution. The solution is based on Riemann invariants and thus exhibits certain similarities to wave solutions of related problems in gas dynamics and chromatography. However, a discontinuity peculiar to the precipitation/dissolution problem prevents unification of these similar solutions into a single, more general theory.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330805
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
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