Bibliothek

Notizen: Abstract An analytical theory of optical pumping of velocity-selective coherent population trapping states in three-level Λ-atoms is presented. The theory is based on an atomic density matrix in the superpositional state representation. The representation introduced for the atomic density matrix directly describes coherent population trapping (CPT) states in a three-level Λ-atom and yields an approximate analytical description for the shape of the two-peak momentum (velocity) distribution of atoms. Optical pumping of velocity-selective CPT states is described in the superpositional state representation as a process of redistribution of atoms in the region of small velocities due to the photon recoil. Typical times of formation of velocity-selective CPT states are found to be inversely proportional to the square of the recoil energy.

Notizen: Abstract We formulate the problem of the stationary point of the operator of radiative relaxation of an atom: the initial distribution among the sublevels of the excited state, whose nonzero eigenvalues (populations) coincide with the populations of the final distribution (after spontaneous decay) among the sublevels of the ground state. We show that these distributions can be expressed in terms of spherical functions of the complex direction. The results are then used to develop a compact analytical representation of the stationary density matrix of atoms interacting with an elliptically polarized monochromatic field.

Notizen: An experimental investigation of the rotational-state dependence of intermolecular interactions for dipole–dipole systems was performed with the aid of light-induced drift. Data are presented of the relative change in collision rate upon excitation, Δν/ν, of HF with respect to polar and nonpolar collision partners (CH3F, CH3Cl, HCl, OCS, and CH4, H2, CO2, respectively). A continuously tunable color-center laser was used to rovibrationally excite HF in the fundamental vibrational band (v=0→1). Both P- and R-branch excitations were studied, with the rotational quantum number ranging from J=0 to 6. By combining Δν/ν for all pairs of P(J) and R(J−1) transitions, the separate v and J dependencies of the collision rate ν are obtained. It is found that for HF–CH3F ν decreases by more than 40%, and for HF–CH4 by only 4%, as J increases from 0 to 6. These data show that the familiar 1/r3 dipole–dipole interaction is highly J dependent. We attribute this to the increased averaging-out of the dipole–dipole interaction as the rotational quantum number increases. A theoretical treatment based upon the first Born approximation for the total cross section of two rotating dipolar molecules is proposed. Comparison between measurements and theoretical results shows good agreement. © 1997 American Institute of Physics.

Notizen: A one-dimensional fluid model for radio-frequency glow discharges is presented which describes silane/hydrogen discharges that are used for the deposition of amorphous silicon (a-Si:H). The model is used to investigate the relation between the external settings (such as pressure, gas inlet, applied power, and frequency) and the resulting composition of the gas and the deposition rate. In the model, discharge quantities such as the electric field, densities, and fluxes of the particles are calculated self-consistently. Look-up tables of the rates of the electron impact collisions as a function of the average electron energy are obtained by solving the Boltzmann equation in a two term approximation for a sequence of values of the reduced electric field. These tables are updated as the composition of the background neutral gas evolves under the influence of chemical reactions and pumping. Pumping configuration and gas inlet are taken into account by adding source terms in the density balance equations. The effect of pumping is represented by an average residence time. The gas inlet is represented by uniformly distributed particle sources. Also the radial transport of neutrals from the discharge volume into the discharge-free volume is important. As the fluid model is one dimensional, this radial transport is taken into account by an additional source term in the density balance equations. Plasma–wall interaction of the radicals (i.e., the growth of a-Si:H) is included through the use of sticking coefficients. A sensitivity study has been used to find a minimum set of different particles and reactions needed to describe the discharge adequately and to reduce the computational effort. This study has also been used to identify the most important plasma-chemical processes and resulted in a minimum set of 24 species, 15 electron-neutral reactions, and 22 chemical reactions. In order to verify the model, including the chemistry used, the results are compared with data from experiments. The partial pressures of silane, hydrogen, disilane, and the growth rate of amorphous silicon are compared for various combinations of the operating pressure (10–50 Pa), the power (2.5–10 W), and the frequency (13.56–65 MHz). The model shows good agreement with the experimental data in the dust free α regime. Discharges in the γ′ regime, where dust has a significant influence, could not be used to validate the model. © 1997 American Institute of Physics.

Notizen: Abstract: We present a scheme for stochastic quantum-state diffusion (QSD) with adaptive noise to calculate the time evolution of an arbitrary observable of an open system. The method is based on the fact that the observable is much less sensitive to adaptive noise than to noise with a random phase. Hence, the individual realisations of the expectation value of the observable stay closer to the average evolution and fewer realisations are required to obtain the ensemble average. This is illustrated by applying QSD to a driven two-level system using both randomly phased and adaptive noise. Applying QSD with adaptive noise to an undriven two-level system enables us to derive a deterministic Schrödinger equation that produces the exact evolution of an arbitrary observable.