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Digitale Medien

Kinetics and mechanism of diethanolamine degradation in aqueous solutions containing carbon dioxide (1984)

Kim, C. J. ; Sartori, G.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 16 (1984), S. 1257-1266

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Details

ISSN: 0538-8066

Schlagwort(e): Chemistry ; Physical Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The problem of diethanolamine (DEA) degradation in gas-treating processes was quantified through a detailed kinetic study. This reaction was found to be catalyzed by CO2, and degradation occurs in a successive manner to 3-(2-hydroxyethyl)oxazolidone-2, to N,N,N′-tris(2-hydroxyethyl)ethylenediamine and then to N,N′-bis(2-hydroxyethyl)piperazine. A reaction mechanism consistent with these observations was proposed and tested through kinetic analyses. A satisfactory kinetic model which can be of practical use was derived.

Zusätzliches Material: 4 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/kin.550161008

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