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Digitale Medien

Structure and Morphology of a Polyether/Polyacrylate Semi-interpenetrating Polymer Network (2000)

Schilling, F. C. ; Katz, H. E. ; Bair, H. E.

Springer

Journal of thermal analysis and calorimetry 59 (2000), S. 83-92

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ISSN: 1572-8943

Schlagwort(e): cationic and photoinitiated polymerization ; DSC ; interfacial mixing ; interpenetrating polymer network (IPN) ; glass transition temperature ; NMR ; quantitative thermal analysis of phases ; reactive epoxy and acrylate systems ; Tg broadening

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract In this study NMR and DSC are used to probe the structure, thermal characteristics and morphology of a network formed from a diepoxide/acrylate system. Separate chemistries are employed to polymerize the diepoxide and acrylate components. The cationic polymerization of the diepoxide exhibits excellent selectivity in producing a crosslinked polyether network without affecting the acrylate monomer. Subsequent photoinitiated free-radical polymerization of the acrylate produces a phase separated, semi-interpenetrating polymer network (SIPN).

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1023/A:1010123610324

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