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  • 11
    Electronic Resource
    Electronic Resource
    Freezing pressures, p, V, T, and self-diffusion data at 298 and 313 K and pressures up to 300 MPa for 1,3,5-trimethylbenzene (1987)
    Springer
    International journal of thermophysics 8 (1987), S. 71-79 
    Details
    ISSN: 1572-9567
    Keywords: freezing pressure ; high pressure ; isothermal compressibility ; p, V, T data ; self-diffusion ; 1,3,5-trimethylbenzene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Mesurements are reported for the melting point of 1,3,5-trimethylbenzene at pressures up to 345 MPa. Self-diffusion coefficients and p, V, T data have been obtained at 298 and 313 K for pressures up to 280 MPa. Isothermal compressibilities have been calculated from the p, V, T results. The freezing pressures at 0.1 MPa correspond to previously reported values for modification III of trimethylbenzene. Equivalent hard-sphere diameters estimated from the melting point and p, V, T data are used to apply the rough hard-spheres theory to the self-diffusion data; the calculations indicate that there is random packing of the particles.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00503225
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  • 12
    Electronic Resource
    Electronic Resource
    Viscosities and intradiffusion coefficients in the ternary system NaCl−MgCl2−H2O at 25°C (1987)
    Springer
    Journal of solution chemistry 16 (1987), S. 835-840 
    Details
    ISSN: 1572-8927
    Keywords: Ternary electrolytes ; NaCl−MgCl2−H2O ; intradiffusion coefficients ; viscosities ; sea-water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The intradiffusion coefficients of Na+, Cl− ions and water and the tracerdiffusion coefficients of Ca2+ ion have been measured in the ternary system NaCl−MgCl2−H2O at 25°C. The intradiffusion coefficients of Mg2+ in this system have been estimated from the corresponding Ca2+ diffusion measurements. Viscosities were measured at the same solution concentrations as were used for the diffusion experiments. Intradiffusion and tracerdiffusion coefficients in a range of temperatures from 5 to 45°C are reported for standard sea-water which is a member of the above ternary set.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00650753
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  • 13
    Electronic Resource
    Electronic Resource
    Glass-transition temperature, electrical conductance, viscosity, molar volume, refractive index, and proton magnetic resonance study of chlorozinc complexation in the system ZnCl2+LiCl+H2O (1974)
    Springer
    Journal of solution chemistry 3 (1974), S. 807-821 
    Details
    ISSN: 1572-8927
    Keywords: Concentrated aqueous solutions ; complex ions ; glass transition temperature ; conductivity ; proton chemical shift ; refractive index ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Several physicochemical techniques have been utilized to study mixed aqueous solutions of ZnCl2 and LiCl along selected pseudobinary composition lines in the concentration range from 2.8 to 22.2m. Measurements of glasstransition temperature, electrical conductance, viscosity, molar volume, refractive index, and proton chemical shift indicate with varying sensitivity that the behavior of these electrolytes is dominated by chlorozinc complexation. The effects of complexation are most sensitively shown by the PMR spectra. In solutions containing more than 6 moles of water per mole of salt, it is probable that several complexation equilibria occur. When the water content is reduced to less than 6 moles per mole of salt, formation of tetrachlorozincate anions appears almost exclusively to be responsible for the composition variation of the physical properties of the solutions. ZnCl 4 = appears to be an even weaker base than ClO 4 − .
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00645686
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  • 14
    Electronic Resource
    Electronic Resource
    A simple differential thermal analysis technique for determining the pressure dependence of solid-liquid and solid-solid transition temperatures (1985)
    Springer
    International journal of thermophysics 6 (1985), S. 275-284 
    Details
    ISSN: 1572-9567
    Keywords: acetonitrile ; benzene ; carbon tetrachloride ; differential thermal analysis ; high pressure ; phase transition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A simple differential thermal analysis technique for determining solid-liquid and solid-solid transition temperatures as functions of pressure is described. The important feature of the technique is the use of a thin-walled ptfe tube both to contain the sample and to transmit pressure to it. The method has been tested at temperatures in the range 200–310 K at pressures of up to 350 MPa. Transition temperatures as functions of pressure are reported for benzene, carbon tetrachloride, and acetonitrile and compared with literature data.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00522149
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  • 15
    Electronic Resource
    Electronic Resource
    Shear viscosity of methanol and methanol + water mixtures under pressure (1985)
    Springer
    International journal of thermophysics 6 (1985), S. 439-450 
    Details
    ISSN: 1572-9567
    Keywords: high pressure ; methanol ; mixtures ; viscosity ; water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Shear viscosities have been measured for methanol up to 400 MPa at 298, 313, and 323 K and for methanol-water mixtures (a) at 0.1 MPa and 278 K and (b) up to 300 MPa at 298 K. Where a comparison is possible the results are in good agreement with literature data. The data for the mixtures are discussed in terms of hydrogen bonding in methanol and water and by the use of excess viscosities.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00508889
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  • 16
    Electronic Resource
    Electronic Resource
    p, V, T and derived thermodynamic data for bromobenzene at temperatures from 278 to 323 K and pressures up to 280 MPa (1987)
    Springer
    International journal of thermophysics 8 (1987), S. 557-565 
    Details
    ISSN: 1572-9567
    Keywords: bromobenzene ; hard-sphere diameter ; high pressure ; internal pressure ; isobaric expansivity ; isothermal compressibility ; p, V, T data
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Experimentally determined p, V, T data are reported for bromobenzene at 278, 288, 298, 313, and 323 K, at pressures up to about 280 MPa or (at 278 and 288 K) a lower pressure slightly below the freezing pressure at the temperature of measurement. Values of the isobaric expansivity, isothermal compressibility, internal pressure, and equivalent hard-sphere diameter, derived from the p, V, T data, are presented.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00503642
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  • 17
    Electronic Resource
    Electronic Resource
    p, V, T and derived thermodynamic data for toluene, trichloromethane, dichloromethane, acetonitrile, aniline, and n-dodecane (1985)
    Springer
    International journal of thermophysics 6 (1985), S. 331-351 
    Details
    ISSN: 1572-9567
    Keywords: acetonitrile ; aniline ; dichloromethane ; high pressure ; n-dodecane ; p,V,T data ; toluene ; trichloromethane
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Experimentally determined p,V,T data are reported for toluene, trichloromethane, dichloromethane, acetonitrile, aniline, and n-dodecane at 278, 288, 298, 313, and 323 K, except for dichloromethane, for which the highest temperature was 298 K. At each temperature, measurements were done at pressures up to about 280 MPa or (for aniline and n-dodecane) at a lower pressure slightly below the freezing pressure at the temperature of measurement. Values of the isobaric expansivity isothermal compressibility and (for toluene, trichloromethane, dichloromethane, and acetonitrile) internal pressure, derived from the p,V,T data, are presented.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00500267
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  • 18
    Electronic Resource
    Electronic Resource
    A general empirical relationship between tracer or self-diffusion coefficients of liquids and pressure (1984)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 641-642 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690300417
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  • 19
    Electronic Resource
    Electronic Resource
    Acid-base reactions in fused alkali borate + TiO2 mixtures (1973)
    Springer
    Journal of materials science 8 (1973), S. 1171-1176 
    Details
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The nature of the titanium-containing phases which crystallize from solutions of TiO2 in fused alkali metal borates, varies with the alkali cation, the mole ratio of alkali oxide to B2O3, and the initial concentration of TiO2. Recrystallization of TiO2 rather than crystallization of complex titanates, is enhanced by the presence in solution of small cations, by a high proportion of B2O3 relative to alkali oxide, and by higher concentrations of TiO2. The crystallization of complex titanates is correlated with the formation of borate groups containing non-bridging oxygens whose existence has been suggested by previous workers.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00632769
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