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  • 11
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract It has been shown that several modifications occurred, over the span of the 17th to 19th centuries, in the agents used to opacify European-made white soda-glass beads that were transmitted as trade goods to northeastern North America. Tin was used at the beginning of the 17th century, followed by Sb later in the century, and then by As during the 18th and 19th centuries. In an attempt to define more closely the transition from Sn-rich to Sb-rich white beads, we analyzed 198 white glass beads from a number of archaeological sites in western New York State. Chemical analysis shows that the arrival of Sb-white soda-glass trade beads began in this region during the period from approximately A.D. 1625–1640, and that they had completely replaced Sn-white beads by A.D. 1675. Specific bead chemistries link a number of the archaeological sites.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 244 (2000), S. 567-573 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Chemical analyses were made of royal blue glass trade beads from two early 17th century, archaeological sites in southern Ontario, Canada and from a glass beadmaking house in Amsterdam, The Netherlands. The results confirm that these beads were all mixed alkali — lime — silica glasses, coloured with Co and with opaque varients opacified with Sn. The groupings by chemistry tend to segregate by bead shapes, so that oval beads group together and circular shaped beads group together. Although the 2 Canadian sites are about 190 km apart, they produced 2 different sets of oval beads of similar chemistry, possibly helping confirm the contemporaneity of the people at both sites. An As/Co atomic ratio of about two may fit with the possible source of Co as a cobalt-arsenide ore (of common name smaltite) from the Hartz Mountains of eastern Germany, a source not far from either Amsterdam or Venice, both well known glass beadmaking centres of the period.
    Type of Medium: Electronic Resource
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