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  • 11
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Phenolic-resin fibre was co-graftpolymerized with methyl methacrylate and methacrylic acid. The weight of the fibre increased by 26% after grafting. The grafted fibre was soaked in silvernitrate solution to introduce silver ion on methacrylic acid in the graft by an ion-exchange reaction, followed by carbonization at 900 °C for 30 min under a nitrogen stream and activation at 900 °C under a steam stream. After activation for 40 min, the resulting fibre showed a silver content of 8.3 wt% a specific surface area of 1300 m2g−1 and antimicrobial activity against Staphylococcus aureus and Escherichia coli. The average crystallite size of the silver in this fibre was 30 nm, which suggests co-graftpolymerization is a useful technique to disperse fine silver particles in the activated carbon fibre. After soaking in flowing tap water for 10 and 20 days, this activated carbon fibre lost about 50 wt% of silver but kept its antibacterial activity.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 29 (1994), S. 4477-4480 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Oriented poly-p-phenylene sulphide (PPS) films (thickness 12 and 75 μm) and PPS powder were carbonized/graphitized after stabilizing by oxidation, in order to examine the effect of sulphur on graphitizability of the resulting carbons. The films and the powder resulted in carbons with a high and a low graphitizability respectively. An “in-plane oriented structure” of the PPS film was the most predominant factor to lead to a high graphitizability, and sulphur in the precursor did not lower the graphitizability when it was subjected to solid-phase carbonization. These phenomena are discussed on the basis of analytical data.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 15 (1996), S. 1481-1483 
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 14
    ISSN: 1573-1561
    Keywords: Hymenoptera ; Formicidae ; Ecitoninae ; army ants ; Eciton ; Labidus ; (E)-β-ocimene ; Dufour gland ; mandibular gland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract The Dufour glands of workers ofEciton burchelli contain a mixture of small quantities of oxygenated compounds, some of which are derived from terpenes, and C17-C25 hydrocarbons. The secretion of the Dufour glands of soldiers was either similar to that of workers, with geranylacetone a significant component, or they contained geranyllinalool in large amounts. The glands of workers and soldiers ofLabidus praedator andLabidus coecus contained (E)-β-ocimene, a new substance for the Dufour glands of ants. 4-Methyl-3-heptanone was the dominant compound in the mandibular glands ofE. burchelli andL. coecus. Skatole and indole were found in the gasters ofL. praedator, and skatole was present in the venom glands of some soldiers ofE. burchelli.
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 46 (1996), S. 521-528 
    ISSN: 1572-8943
    Keywords: methacrylamide-montmorillonite intercalation ; thermal stability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Thermal stability of methacrylamide intercalated octadecylammonium montmorillonite (OD-M/MA) is limited by rapid desorption of methacrylamide (MA) at 140°C. It was improved by γ-irradiation. The irradiation intercalation complex OD-M/MA γ shows significant shift of the whole desorption process towards higher temperatures. However, part of the adsorbed organic material is released at 50°C signalizing presence of some volatile fractions. Decomposition products of the intercalated material and long-chain alkylamides in the acetone extract indicate complex reactions between MA and octadecylammonium chains. An additional swelling of the silicate structure occurs after γ-ray initiation and is probably related to the reaction products with a certain degree of cross-linking in the interlayers.
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 31 (1996), S. 3403-3407 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A silver chelate of 2-(4-thiazolyl)-benzimidazole, dodecyltrimethylammonium cation and hexadecylpyridinium cation have been intercalated between montmorillonite, and the resulting samples were subjected to examination of their thermostabilities by thermogravimetry and carbon dioxide evolution analysis up to 500 °C in air. The degradation behaviour of the intercalant was significantly changed by intercalating between the montmorillonite layers. Two quaternary ammonium cations were released from the montmorillonite both at the same temperature, which was higher than those for the quaternary ammonium cations themselves. This relation was also observed in the case of 2-(4-thiazolyl)-benzimidazole. The improvement of the thermostability after intercalation can be attributed to the bonding between the intercalant and the host montmorillonite layers.
    Type of Medium: Electronic Resource
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  • 17
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Rice hull was moulded into a tube (outer diameter: 54 mm; inner diameter: 17 mm, length: c. 170 mm) by use of an extruder and then carbonized in nitrogen atmosphere below 1000 °C. Ash content of the hull was 16 wt%, of which c. 94 and 4 wt% were SiO2 and K2O, respectively. Carbon yield and shrinkage of the mould after carbonization at 1000 °C were 42 wt%, and 43 vol%, respectively. The bulk density increased with rising of carbonization temperature to reach to 0.93 g ml−1 at 1000 °C via 0.82 g ml−1 at 500 °C. The largest compressive strength of 3.6 MPa was obtained after carbonization at 1000 °C. No micropore was developed after carbonization, and the total pore volume measured by a mercury porosimeter was 0.25–0.31 ml g−1 after carbonization. These data were compared with those of charcoal.
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 31 (1996), S. 4307-4310 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Toluene solutions of hydrophobic smectite (SAN) and polypropylene (PP) were mixed thoroughly. Trimethylsilylated SAN was also used to examine the effects of the surface modification. In both the smectites, the resulting mixtures were transparent but the stacked layer structures were retained, with expansion of the interlayer distance from 2.26 nm to ∼5 nm. The PP containing the fine SAN filler particles was prepared after removal of toluene, followed by mixing with the PP to produce a 3 wt% SAN content. The SAN particles were more finely dispersed in the resulting composites than was achieved by conventional mechanical mixing, but the mechanical properties were not improved remarkably. The trimethylsilylation conferred no favourable effect on the mechanical properties of the composite.
    Type of Medium: Electronic Resource
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  • 19
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 29 (1994), S. 11-14 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Five antimicrobial ammonium cations were intercalated into two clay minerals (saponite and montmorillonite) by using ion-exchange reaction. About 90% of the cation exchange capacities of the clay minerals were replaced by ammonium ions with a few exceptions. The resultant complexes exhibited antimicrobial activity against both Staphylococcus aureus and Escherichia coli. After heating to 250 °C, the antimicrobial activity was kept for the complexes with aromatic ammonium ions but not for those with aliphatic ammonium ions. The complexes were treated with deionized water and a 3% aqueous solution of sulphuric acid to examine the elution of the ammonium ions. The elution finished within 1 day, with retention of 80% of the aromatic ammonium ions. Aliphatic ammonium ions remained in smaller amounts.
    Type of Medium: Electronic Resource
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  • 20
    ISSN: 1432-8798
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Growth characteristics of a wide range of influenza A viruses from different mammals and bird species were examined in an established line of canine kidney (MDCK) cells at an ordinary (37°C) and a high temperature (42°C). Although all viruses employed in the present study possessed a capability of replicating at 37°C, virus growth at 42°C showed considerable variation and reflected differences in the natural hosts of the isolates. All reference strains and isolates from bird species grew well in the MDCK cells maintained at 42°C, but human viruses did not, showing an asymmetrical growth behavior. In contrast to this, growth of swine and equine viruses showed growth characteristics intermediate between human and avian viruses. Of the two swine viruses examined, replication of one strain occured equally well at both temperatures and another failed to grow at 42°C. Similarly, two of the three equine viruses tested belonging to H3N8 antigenic subtypes grew at 42°C. However, the results obtained from comparison of plaque sizes and growth curves indicated that the replication of the above swine and equine viruses was restricted under a stringent temperature when compared to avian viruses. The detailed analysis of cloned viruses revealed that some of the swine and equine viruses contained two variants which are readily distinguished by growth behavior at 42°C. Genome analysis of parental and virus clones by oligonucleotide mapping and migration profiles of RNA segments did not detect any differences among the above variants exhibiting the asymmetrical growth characteristics at 42°C.
    Type of Medium: Electronic Resource
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