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  • 11
    ISSN: 1432-0428
    Keywords: Keywords IDDM ; NIDDM ; population-based trial ; HbA1c ; care quality.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Since 1990 in most Eastern European countries health care systems have been decentralized or are undergoing the processes of decentralization. Increasingly, diabetic patients are no longer treated by diabetologists but by non-specialized physicians. During the same period structured treatment and teaching programmes have been introduced and health care is increasingly influenced by the St. Vincent declaration. To show the effect of these changes on the quality of diabetes care 90 % (n = 244) of all insulin-treated diabetic patients aged 16 to 60 years and living in the city of Jena (100 247 inhabitants) were studied in 1994/1995. The results were compared with the baseline examination of 1989/1990 (n = 190). HbA1c (HbA1c/mean normal) in IDDM patients under specialized care was similar in 1994/1995 (1.54 ± 0.27, n = 47) to 1989/1990 (1.52 ± 0.31, n = 131, p = 0.0018), but higher under non-specialized care (1.71 ± 0.38, n = 80, p = 0.0087). In the total group of NIDDM patients there was no significant change in HbA1c (1994/1995: 1.75 ± 0.4, n = 117, vs 1989/1990: 1.78 ± 0.4, n = 59, p = 0.67), but with a tendency to higher HbA1c under non-specialized (1.81 ± 0.4, n = 79) compared to specialized care (1.66 ± 0.39, n = 38, p = 0.06). Incidence of severe hypoglycaemia (IDDM 0.13; NIDDM 0.04), ketoacidosis (0.02; 0.01) and the prevalence of nephropathy (21 %; 35 %) and neuropathy (24 %; 38 %) remained unchanged in comparison to 1989/1990, whereas there was an increase in the prevalence of diabetic retinopathy. Specialized care is mandatory for patients with IDDM. [Diabetologia (1997) 40: 1350–1357]
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 11 (1977), S. 561-576 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: It is known that the 2l+1 spherical harmonics Ylm can be transformed into cyclically equivalent orbitals, of which only a few examples have so far been given explicitly. In this article the totality of such cyclic sets is derived.It is demonstrated that other kinds of equivalent spherical harmonics do not exist.Finally a set of five equivalent d orbitals related to icosahedral symmetry is introduced.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 28 (1985), S. 287-295 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The potential energy of a homonuclear X4 molecule is an invariant of the atom permutation group S4 acting on the internal coordinates of X4. It is shown by means of invariant theory that six algebraically independent invariants and five additional invariants are required to express the general invariant function for this group. Explicit expressions for these 11 invariants are given.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 54 (1971), S. 1299-1303 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A computer program is described, which generates a simplified pictorial representation of computed molecular orbitals. As examples, the highest occupied MO's of the two C8-rotamers of the cyclopropylcarbinylcation (C4H7+), of pyridine and of barrelene (bicyclo[2.2.2]octatriene) are given.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 54 (1971), S. 1575-1580 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A possibility of correlating electronic and photoelectron spectra is discussed, using trans-azomethane as an example. The Coulomb and exchange integrals required were obtained by three semi-empirical SCF-methods: MINDO/2, CNDO/2, and a modified CNDO method. The orbital energies were taken as minus the corresponding experimental ionization potentials. The sequence of the transition energies ΔE (ns → π*) Δ E (na → π*) 〈 ΔE (π → π*) is found to be different from the ionization potential sequence IP (ns) 〈 IP (π) 〈 IP (na), in agreement with previous spectroscopic studies; the results support the latest view that the π → π* transition of the azo group occurs at around 12 eV.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 55 (1972), S. 1745-1752 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: For a π-molecular system containing two symmetry-equivalent heteroatoms, a qualitative relationship between the difference in the n-ionization potentials (ΔIP) and the difference between the n → π* excitation energies (ΔΔE) is derived, using semi-localized orbitals as a basis. The comparison between ΔIP and ΔΔE yields information about the energies and/or the shapes of the two lone pair MO's in the model system. The results provide further insight into ‘through space’ and ‘through bond’ interaction concept introduced by Hoffmann.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 17
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The photocelectron spectra of nortricyclene (=tricyclo[2.2.1.02,6]heptane) and of triasterane (=tetracyclo[3.3.1.02,8.04,6]nonane) have been recorded and a tentative assignment of the bands has been put forward on the basis of MINDO/2 SCF calculations.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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