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  • 1
    Electronic Resource
    Electronic Resource
    Continuous removal of radioactive cobalt from water (1987)
    Springer
    Journal of radioanalytical and nuclear chemistry 119 (1987), S. 77-80 
    Details
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract More than 99% of radioactive cobalt can be removed from water by precipitation as cobalt/III/ hydroxide. The process is continuous and uses either sodium hypochlorite or oxygen and calcium sulfite to oxidize the cobalt. Carbonate and phosphate interfere with cobalt removal, but the process has potential for other applications such as thallium removal and sewage treatment.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02169834
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  • 2
    Electronic Resource
    Electronic Resource
    Formation of plutonium/IV/ colloid from plutonyl cations (1988)
    Springer
    Journal of radioanalytical and nuclear chemistry 126 (1988), S. 429-433 
    Details
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Solutions of plutonyl cations in dilute acids gradually form Pu/IV/ polymer under the influence of alpha radiations. These systems have properties that can be illuminated by assuming conditions to be near equilibrium and constrained by mass conservation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02164546
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  • 3
    Electronic Resource
    Electronic Resource
    The ratio Pu(V)/Pu(IV) in natural water (1989)
    Springer
    Journal of radioanalytical and nuclear chemistry 137 (1989), S. 75-78 
    Details
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The behavior of the ratio Pu(V)/Pu(IV) depends on whether the symbols represent absolute concentrations of soluble species, or fractions of the total soluble plutonium, or insoluble, colloidal substances.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02164561
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Charge balance vs. charge conservation for plutonium (1991)
    Springer
    Journal of radioanalytical and nuclear chemistry 154 (1991), S. 133-137 
    Details
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A recent paper about plutonium disproportionation confuses charge balance with charge conservation. To explain disproportionation, impossible solutions in which the charges do not balance were proposed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02162671
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  • 5
    Electronic Resource
    Electronic Resource
    Temperature and pentavalent plutonium (1998)
    Springer
    Journal of radioanalytical and nuclear chemistry 230 (1998), S. 289-289 
    Details
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Two reasons for understanding the increasing fraction of pentavalent plutonium with rising temperature in dilute acid are presented. The reasons make the results of calculations easier to understand.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02387482
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  • 6
    Electronic Resource
    Electronic Resource
    The Auto-Reduction of Hexavalent 239Pu in Acid Solution (2000)
    Springer
    Journal of radioanalytical and nuclear chemistry 246 (2000), S. 429-430 
    Details
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Historical measurements on the alpha-particle reduction of hexavalent 239Pu can be interpreted as a succession of near-equilibrium steps. The phenomenon can be simulated by plotting the distribution of the oxidation states for decreasing values of the Pu oxidation number.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1006784221063
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  • 7
    Electronic Resource
    Electronic Resource
    Work integrals for plutonium (1991)
    Springer
    Journal of radioanalytical and nuclear chemistry 153 (1991), S. 111-116 
    Details
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Free energy changes in Pu disproportionation reactions can be measured by integrating the reaction isotherm with respect to one of the reaction products. Separate integrations can be made for the isotherms of the component reactions contributing to the equilibrium.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02164871
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  • 8
    Electronic Resource
    Electronic Resource
    Actinide pollutants and the oxygen/water couple (1992)
    Springer
    Journal of radioanalytical and nuclear chemistry 164 (1992), S. 153-156 
    Details
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The redox potential of environmental water influences the speciation of pollutants like plutonium. This potential cannot be reliably predicted from diagrams for irreversible couples like oxygen/water.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02163767
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  • 9
    Electronic Resource
    Electronic Resource
    Activation of uranium metal (1986)
    Springer
    Journal of radioanalytical and nuclear chemistry 103 (1986), S. 199-202 
    Details
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Treatment of uranium with hydrochloric or hydrobromic acid produces an adherent layer of hydride on the metal surface. When this hydride is decomposed by heat in a vacuum, the resulting metal surface reacts immediately with hydrogen at ambient temperature.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02166566
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    Paper (German National Licenses)
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  • 10
    Electronic Resource
    Electronic Resource
    Charge balance equations for plutonium (1993)
    Springer
    Journal of radioanalytical and nuclear chemistry 175 (1993), S. 281-285 
    Details
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Charge balance equations can be used to obtain relationships among oxidation states in plutonium solutions. These equations are prepared from the initial conditions in the solution; they can be checked using equations of mass and charge conservation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02165069
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