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  • 1
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Analytical chemistry 66 (1994), S. 2816-2819 
    ISSN: 1520-6882
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 89 (1985), S. 1070-1072 
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie , Physik
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 1129-1135 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Molecular-dynamics calculations were performed to simulate ion beam deposition of diamond-like carbon films. Using the computationally efficient analytical potentials of Tersoff and Brenner we are able to simulate more than 103 carbon atom impacts on {111} diamond, so that steady-state film properties can be computed and analyzed. For the Tersoff potential, we achieve sp3 fractions approximately half of the experimentally observed values. For the more refined hydrocarbon potentials of Brenner the fraction of tetrahedrally coordinated atoms is much too low, even if structures with densities close to diamond are obtained. We show, that the sp3 contents calculated with Tersoff's potential are an artifact related to the overbinding of specific bonding configurations between three- and fourfold coordinated sites. On the other hand, we can prove, that the range for the binding orbitals represented by the cutoff function is too short in Brenner's parametrization. If an increased C–C interaction cutoff value is chosen, we achieve a distinct improvement in modeling the sp3 content of deposited ta-C films. As a result we compute sp3 fractions which lie between 52% and 95% for the C+ ion energies E=30–80 eV and are in reasonable agreement with recent experimental studies. © 2000 American Institute of Physics.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 66 (1995), S. 3069-3070 
    ISSN: 1089-7623
    Quelle: AIP Digital Archive
    Thema: Physik , Elektrotechnik, Elektronik, Nachrichtentechnik
    Notizen: A routing circuit for Oxford Instrument's PCA II multichannel analyzer card is described. The circuit allows recording of events requiring coincident signals from two out of four detectors. As an example, the use of the routing circuit in a time-differential perturbed angular correlation spectrometer is outlined. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 66 (1995), S. 4350-4355 
    ISSN: 1089-7623
    Quelle: AIP Digital Archive
    Thema: Physik , Elektrotechnik, Elektronik, Nachrichtentechnik
    Notizen: We have shown that a simple nuclear magnetic resonance spin-tagging sequence for spatial encoding of the longitudinal magnetization, combined with an imaging sequence, can be used to measure flow and diffusion in granular materials. Using this technique, experiments have been performed to study flow and diffusion profiles during convection induced by the vertical shaking of a container (39 mm diameter) filled with a granular medium. We have shown that maximum diffusion and displacements occur in a thin boundary layer near the container's walls. The observed flow profiles are predominantly flat with relatively small positive displacements across the container with the exception of the boundary layer, where increasingly negative displacements are observed as the container's edges are approached. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Oxford, UK : Blackwell Science Ltd
    European journal of soil science 52 (2001), S. 0 
    ISSN: 1365-2389
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Geologie und Paläontologie , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: A new sampling technique for measuring the concentrations of trace gases (CH4, CO2 and N2O) in the soil atmosphere from well-defined depths is described. Probes are constructed from silicone tubing closed with silicone septa on both ends, thereby dividing an inner air space from the outer soil atmosphere without a direct contact. The gas exchanges between the inner and outer atmosphere only by diffusion through the walls of the silicone tube. Tests revealed that the gases N2O, CO2 and CH4 in the enclosed space reached 95% equilibrium with the surrounding atmosphere at 20°C within 7 h or faster. The probe measurements are reproducible: the standard deviation of samples taken from 26 probes stored in the laboratory atmosphere equalled that of a standard gas. The probes can easily be constructed and installed at specified depths in the soil.The method has the following advantages compared with other methods that use spaces with holes in them for gas exchange: (i) the silicone probe enables trace gases to be sampled in wet soils, including ones that are waterlogged or temporarily saturated; (ii) the sampling itself does not create low pressure and hence does not create mass flow in the soil matrix from undefined depths; and (iii) the probe can be made to take samples of gas of any required size. The silicone probes did not show ageing effects during 18 months of use in the field in a mineral soil under grass. The probes yielded comparable results: three probes inserted at 5 cm depth in a uniformly treated 100-m2 plot provided nearly identical average trace gas concentrations within the measurement period.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Oxford, UK : Blackwell Science Ltd
    Grass and forage science 52 (1997), S. 0 
    ISSN: 1365-2494
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: In order to assess the effects of future elevated atmospheric CO2 concentrations on yield, mineral content and the nutritive value of mixed swards of perennial ryegrass (Lolium perenne L.) and white clover (Trifolium repens L.), both species were grown as monocultures and as different mixtures and were exposed season-long to ambient (380 p.p.m.) and elevated (670 p.p.m.) CO2 concentrations in open-top chambers. Mini-swards were cut four times at about monthly intervals at a height of 5 cm, dry-matter yields were determined and content of macroelements (N, P, K, S, Mg, Ca, Na) and crude fibre, crude protein and ash content were measured. The CO2-related increase in seasonal yield amounted to 16–38% for white clover monocultures, 12–29% for mixed swards and 5–9% for ryegrass monocultures. The white clover content of all swards was significantly enhanced by elevated CO2. The K and Na content of total yield was decreased by high CO2 but did not fall below the minimum requirements for ruminants. As the Ca content of total yield was increased by elevated CO2 and the P content was not changed, the Ca/P ratio of total yield was increased and exceeded values required for animal nutrition. The crude protein content of total yield was reduced by high CO2 at the beginning of the growing season only and was increased by elevated CO2 in the course of the experiment, whereas crude fibre content was decreased throughout the season, sometimes falling below the minimum requirement for ruminants. Removal of N, P, S, Mg and Ca by cutting was significantly enhanced because of CO2 enrichment. The results show that, besides the positive effect of rising atmospheric CO2 on dry-matter yield of white clover/ryegrass swards, impacts on the nutritive value should be expected. Possible changes in species composition and implications for grassland management are briefly discussed.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 176-186 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The time evolution of the transient enhanced diffusion and of the electrical activation of boron in crystalline silicon during thermal annealing subsequent to boron ion implantation is modeled by a system of diffusion-reaction equations for the dopant species and the silicon point defects. The concept of point defect impurity pair diffusion under equilibrium conditions is used to describe the diffusion process. Outdiffusion of implantation-induced silicon self-interstitials and the kick-out reaction Bi(large-closed-square)Bs+I are assumed to be the leading mechanisms for boron activation. In the case of low-dose boron ion implantation, we start from a defect distribution of Gaussian shape with one interstitial per implanted boron atom. For higher boron doses, the area density of this interstitial distribution is constant, but the depth position of its peak depends on boron dose. Local equilibrium for the reactions between the point defects and the boron species is postulated to be realized before the onset of diffusion. The computed boron depth profiles are compared to data from the literature. Implantation doses from 2×1014 cm−2 up to 5×1015 cm−2 are analyzed, annealing temperatures and times are considered over the ranges 800–1000 °C and 10 s–8 h, respectively. Although this approach is characterized by a number of simple assumptions, essential deficiencies are only found in certain cases of annealing subsequent to high-dose boron implantation. Trapping of free interstitials by extended defects seems to become important at low temperatures and for long annealing times. If the depth region with maximum boron concentration is in its as-implanted state close to amorphization, a boron overactivation which is beyond the present model can be found. For all other cases it is possible to achieve a reasonable modeling of transient enhanced diffusion and of electrical activation. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 58 (1987), S. 1694-1698 
    ISSN: 1089-7623
    Quelle: AIP Digital Archive
    Thema: Physik , Elektrotechnik, Elektronik, Nachrichtentechnik
    Notizen: A four-detector time-differential perturbed angular correlation spectrometer controlled by an inexpensive microcomputer is described. The use of twin-single-channel analyzers permits each detector to identify both gamma rays in the cascade. An improved gating logic system reduces the MCA/computer deadtime and allows larger sample activity and faster data accumulation. The twin-single-channel analyzer and gating circuit additions also permit simultaneous accumulation of two statistically independent sets of four-channel spectra. The spectrometer provides on-line display of raw data and the perturbation function derived from either set of four-channel spectra.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 64 (1994), S. 422-424 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We describe the fabrication and characterization of self-assembled gold island arrays on diblock-copolymer thin films. The natural tendency of these polymers to form ordered phases is used to induce selective aggregation of evaporated gold metal during an annealing process. We obtain well-defined, nanoscale island arrays aligned with one of the copolymer blocks. Near perfect segregation is achieved between the two domains. Two types of diblock-copolymer systems are discussed, together with the resulting island patterns.
    Materialart: Digitale Medien
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