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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 5545-5551 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Soft-magnetic cores with nanoscale bcc structure were fabricated by consolidation of amorphous or nanocrystalline Fe86Zr7B6Cu1 (at. %) powder using a hot-pressing machine. The most appropriate process to fabricate nanocrystalline Fe86Zr7B6Cu1 soft-magnetic compacts with high density is the direct consolidation of the amorphous powder into nanocrystalline compacts. This process is superior to the annealing method of the amorphous compacts produced from the amorphous powder. The main reason is that the former process fully utilizes the low viscosity of the amorphous alloy before the crystallization temperature. On the other hand, the consolidation of the nanocrystalline powder prepared by annealing of the amorphous powder is an unsuitable process because of the lack of the decrease in viscosity. The nanocrystalline Fe86Zr7B6Cu1 compact obtained by pressing the amorphous powder for 200 s at 853 K and 1.5 GPa has a high density of 99.9% of the theoretical density and exhibits good soft-magnetic properties. The saturation magnetization Bs, coercive force Hc, maximum permeability μmax, effective permeability μe at 1 kHz and 0.8 A/m, and core loss Wh at 10 kHz and 0.1 T are 1.56 T, 33 A/m, 4300, 1300, and 37 W/kg, respectively. It is therefore established that the present compact possesses good soft-magnetic properties combined with high magnetization.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 4215-4215 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A new class of Fe-, Co-, Ni-, Cu-, and Ge-based ductile ribbons in which an amorphous matrix containing less than 12 vol. % of a fine dispersion of 0.1–3-μm size particles of immiscible elements M=Pb, Bi, Sn, or In have been produced by a modified melt-quenching technique. The Fe- and Co-based alloys containing Bi and Pb are found to be ferromagnetic above room temperature and also superconducting at temperatures in a range 7–9 K depending on the alloy. The saturation magnetization in these usual alloys range from 92 emu/gm for Co-Si-B-Pb-Bi to 15 emu/g for Fe-P-Pb-Bi at 77 K. At the superconducting transition the resistivity typically is found to drop by 2–3 orders of magnitude with a transition width ∼0.5 K before the "zero'' resistance value is reached. In all the alloys studied the T dependence of the resistivity shows a typical metallic behavior despite its high magnitude (a few thousand μΩ cm in some cases). Extremely high values are found for the upper critical fields (1.6–1.72 T at 4.2 K) with critical current densities typically around 1.3×107 A m−2 at 4.2 K. For Ge-Pb-Bi-Sn Hc2 values of 5 T are obtained at 3 K. Along with detailed studies of magnetic and superconducting properties, extensive TEM, and x-ray characterization data will also be presented. Attempts to explain the above described behavior in terms of proximity, percolation, and surface properties at the dispersed Pb, Bi particles are found to be unsatisfactory. As far as we know there exists no theory that can explain the co-existence of ferromagnetism and superconductivity of the type described above. Time permitting, we will also discuss our recent work on high Tc oxide materials produced by melt-quenching techniques. Thus amorphous composite materials exhibiting unique and useful characteristics which cannot be achieved for homogeneous amorphous alloys can be produced by melt quenching. These materials are of importance both for scientific and engineering points of view.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 4491-4493 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A glass transition, followed by a supercooled liquid region was found in wide composition ranges of 0–65 at % Co and 1.5–7 at % Ln in Fe80−x−yCoxLnyB20 (Ln=Nd, Sm, Tb, or Dy) amorphous alloys. The supercooled liquid region (ΔTx) shows the largest value of 41 K for the Fe47Co30Sm3B20 alloy. An internal equilibrium state leading to the disappearance of the previous thermal history was achieved within a temperature interval of 15 K. The Fe–Co–Ln–B amorphous alloys exhibit soft ferromagnetism with saturated magnetization (Bs) of 0.84–1.66 T and coercivity (Hc) of 5.0–36 A/m. A high magnetostriction (λs) exceeding 40×10−6 was also observed in the composition range of 0–10 at % Co and 1.5–3 at % Ln (Ln=Sm, Tb, or Dy). The highest λs reaches 58×10−6 for Fe68.5Co10Ln1.5B20 (Ln=Sm or Tb), which is higher than the highest value (44×10−6) for previously reported amorphous alloys. All the Fe68.5Co10Ln1.5B20 amorphous alloys have good bending ductility. The tensile strength, Vickers hardness and Young's modulus of the Fe68.5Co10Sm1.5B20 alloy are 3220 MPa, 990 and 76.5 GPa, respectively. The combination of high λs, high Bs, low Hc, large ΔTx, good ductility and high mechanical strength is promising a new type of ferromagnetic bulk amorphous alloy. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A mostly single bcc phase with nanoscale grain sizes of 10 to 20 nm was found to form by annealing amorphous Fe-Zr-B, Fe-Hf-B, and Fe-M-B-Cu(M=Ti, Zr, Hf, Nb, and Ta) alloys for 3.6 ks in the range of 723 to 923 K. The high permeability (μe) above 10 000 at 1 kHz combined with high saturation magnetization (Bs) above 1.5 T was obtained for the bcc alloys. The highest μe and Bs values reach 14 000 and 1.7 T for Fe91Zr7B2, 20 000 and 1.55 T for Fe87Zr7B5Cu1, and 48 000 and 1.52 T for Fe86Zr7B6Cu1. Magnetostriction (λs) decreases significantly by the phase transition from amorphous to bcc phase and is measured to be 1 × 10−6 for the bcc Fe86Zr7B6Cu1 alloy. The small λs as well as the small grain size is concluded to be the reason for the good soft magnetic properties. The lattice parameter of this bcc phase is 0.2870 nm being larger than that of pure α-Fe. The small λs seems to be achieved by the dissolution of solute elements above an equilibrium solubility limit. The bcc Fe86Zr7B6Cu1 alloy also shows the low core loss of 0.066 W/kg at 1 T and 50 Hz, which is considerably smaller than that of amorphous Fe78Si9B13 and bcc Fe-3.5mass%Si alloys in practical uses as core materials in transformer.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 69 (1991), S. 2728-2730 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An Al75Pd25 decagonal (D) phase changes to an F-type icosahedral (I) phase by the substitution of 3 at. % Cr for Al in a rapidly solidified state. The coexisting I and D phases in a rapidly solidified Al73Pd25Cr2 alloy have a close orientation relationship, in which a tenfold axis of the D phase coincides with a fivefold axis of the I phase.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 3316-3322 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Magnetic core properties, core loss, permeability, and saturation magnetic induction of bcc-nanocrystalline Fe–M–B (M=Zr, Hf, and Nb) alloys produced by annealing a melt-spun amorphous phase were investigated in a ring-shaped form with the aim of clarifying the application potential as a core material. The bcc alloys exhibit high saturation induction (Bs) from 1.49 to 1.63 T combined with high permeability (μe) from 22 000 to 32 000 at 1 kHz and 0.4 A/m. The bcc Fe–M–B (M=Zr, Hf, or Nb) alloys also show low core losses (W) from 1.4×10−1 to 2.1×10−1 W/kg at 50 Hz and 1.4 T and from 1.70 to 2.50 W/kg at 1 kHz and 1.0 T. The W values attained for the bcc Fe–M–B (M=Zr, Hf, and Nb) alloys are smaller by 60%– 90% at 50 Hz and 1.4 T and 50%–70% at 1 kHz and 1.0 T, as compared with those for an amorphous Fe78Si9B13 alloy in practical use as a transformer core material. The low W values for the bcc-nanocrystalline alloys are presumably due to the small anomaly factor comparable to a Co-based amorphous alloy. The comparison of the present data with those for the amorphous Fe78Si9B13 alloy indicates that the bcc-nanocrystalline Fe–M–B (M=Zr, Hf, and Nb) alloys are promising for practical use as core materials.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 67 (1995), S. 2008-2010 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report the production of full strength compacts of metallic glass by warm extrusion of powders at the supercooled liquid state just above the glass transition temperature. The alloy used was Zr65Al10Ni10Cu15 (at. %) which has the lowest viscosity among Zr-based metallic glasses with large supercooled liquid region. The tensile strength and Young's modulus of the glassy powder compacts were 1520 MPa and 80 GPa, respectively, which are similar to that obtained in the as-cast bulk alloy and melt-spun ribbon. This opens up possibilities of producing high strength amorphous alloys with complex shapes. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 75 (1999), S. 340-342 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Nanocrystalline composites with the grain size less than 10 nm were produced by annealing of Cu-mold cast Zr70−x−yTixNi10Cu20Aly (X=5–7.5 and Y=10–15 at %) bulk amorphous alloys. The nanostructured alloys show increased tensile strength at the volume fraction of nanoparticles less than 30%. The microstructure of the amorphous alloys was found to contain medium range order (MRO) domains, which uniformly distributed in the amorphous matrix. We suggest that MRO domains provide nucleation sites for precipitation of the primary crystals and lead to the formation of nanocrystalline composites. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 75 (1999), S. 3644-3646 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Rapidly solidified ribbons of nanocrystal-forming Zr–Cu–Pd–Al metallic glasses were prepared at various liquid temperatures (TL). Differential scanning calorimetry (DSC) traces show clearly the influence of the liquid states on the thermal properties and crystallization process. Namely, with increasing TL, the exothermal peaks of the DSC traces shift to higher temperatures, the super-cooled-liquid region ΔTx increases, and the decomposition of the metastable compound Zr2(Cu, Pd) becomes more difficult. These results suggest that the liquid state strongly controls the crystallization process of the nanocrystal-forming metallic glasses. This behavior may originate from the variation of the quenched-in nuclei, which highly depends on the short-range-order domains in liquid with different TL. We suggest that the stronger attractive interaction in Zr–Pd, which exhibits large negative mixing enthalpy, leads to the short-range order domains. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have found that an amorphous phase with a wide supercooled liquid region reaching 85 K before crystallization is formed in Fe–(Co, Ni)–(Zr, Nb, Ta)–B, Fe–Co–(Zr, Nb)–(Mo, W)–B and Co–Fe–Zr–B systems. The high stability of the supercooled liquid enabled the production of bulk amorphous alloys with diameters up to 5 mm by copper mold casting. These amorphous Fe–(Co, Ni)–M–B alloys exhibit good soft magnetic properties, i.e., saturation magnetization of 0.95 to 1.1 T, low coercivity of 1 to 8 A/m, Curie temperature of 560 to 590 K and low magnetostriction of 8–14×10−6. The effective permeability of the Co–based alloys exceeds 25 000 at 1 kHz and keeps high values above 5000 at the high frequency of 1 MHz. The permeability at 1 MHz is much higher than those for any kinds of soft magnetic materials. The frequency at which the imaginary part of permeability shows a maximum is also about 1 MHz. The success of synthesis of new Fe- and Co-based amorphous alloys with good soft magnetic properties and high glass-forming ability is promising for future development of a new type of soft magnetic material. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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