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  • Key words. Natural configurations, shape memory, dissipation, hysteresis, Helmholtz potential, entropy, phase transition, Austenite, Martensite, interfacial energy, evolution equation, latent energy, multiconfigurational.  (1)
  • Physics  (1)
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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Zeitschrift für angewandte Mathematik und Physik 50 (1999), S. 459-496 
    ISSN: 0044-2275
    Schlagwort(e): Key words. Natural configurations, shape memory, dissipation, hysteresis, Helmholtz potential, entropy, phase transition, Austenite, Martensite, interfacial energy, evolution equation, latent energy, multiconfigurational.
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Mathematik , Physik
    Notizen: Abstract. The thermomechanical behavior of a shape memory wire is modeled based on a theory that takes cognizance of the fact that the body can possess multiple natural configurations [1]. The constitutive equations are developed by first constructing the form of the Helmholtz potential (based on different modes of energy storage), and dissipation mechanisms. The internal energy includes contributions from the strain energy, the latent energy, the interfacial energy and thermal energy. The entropy of the system includes the"entropy jump" associated with the phase transition.¶The role of the rate of mechanical dissipation as a mechanism for entropy generation and its importance in describing the hysteretic behavior is brought out by considering the difference between hysteretic and non-hysteretic (dissipation-less) behavior.¶Finally, simple linear or quadratic forms are assumed for the various constitutive functions and the full shape memory response is modeled. A procedure for the determination of the constants is also indicated and the constants for two systems (CuZnAl and NiTi) are calculated from published experimental data (see [2, 3]). The predictions of the theory show remarkable agreement with the experimental data. However, some of the results predicted by the theory are different from the experimental results reported in Huo and Muller [2] We discuss some of the issues regarding this discrepancy and show that there appears to be some internal inconsistency between the experimental data reported in Figure 6 and Figure 9 of Huo and Muller [2] (provided they represent the same sample).
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 2011-2016 
    ISSN: 0360-6376
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Emulsion polymerization of vinyl acetate with sodium laryl sulfate as emulsifier and potassium persulfate as initiator was studied and found to follow the rate equation suggested by Harriot: \documentclass{article}\pagestyle{empty}\begin{document}$ R_p = k_p \left( M \right)_p \left( {\frac{{2kd\left( {\rm I} \right)_w V_w V_p }}{{k_t }}} \right)^{{1 \mathord{\left/{\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} $\end{document}
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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