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  • 1
    Electronic Resource
    Electronic Resource
    Kinetics and mechanism of the oxidation of glycolaldehyde by tetrachloroaurate(III) (1998)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 30 (1998), S. 613-619 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of the reaction between glycolaldehyde (GA) and tetrachloroaurate(III) in acetic acid-sodium acetate buffer has been studied. The reaction is first-order with respect to [AuIII] as well as [GA]. Both H+ and Cl- ions retard the rate of reaction. AuCl4-, AuCl3(OH2), and AuCl3(OH)- are the reactive species of gold(III) with gradually increasing reactivity. A reaction mechanism involving two-electron transfer rate determining steps has been proposed. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet: 30: 613-619, 1998
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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