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Kinetics and mechanism of the oxidation of glycolaldehyde by tetrachloroaurate(III) (1998)

Sen, Pratik K. ; Bilkis, A. B. ; Gupta, Kalyan K. Sen

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 30 (1998), S. 613-619

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The kinetics of the reaction between glycolaldehyde (GA) and tetrachloroaurate(III) in acetic acid-sodium acetate buffer has been studied. The reaction is first-order with respect to [AuIII] as well as [GA]. Both H+ and Cl- ions retard the rate of reaction. AuCl4-, AuCl3(OH2), and AuCl3(OH)- are the reactive species of gold(III) with gradually increasing reactivity. A reaction mechanism involving two-electron transfer rate determining steps has been proposed. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet: 30: 613-619, 1998

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

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