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  • 1
    ISSN: 1520-5827
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 57 (1986), S. 2332-2338 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A stainless-steel piston cylinder dilatometer (volume ∼100 cm3), designed for use in microgravity, was tested and modified for the purpose of obtaining the polymerization kinetics of monodisperse polystyrene latexes, as well as the latexes themselves. A low-speed, oscillatory agitation (10 rpm, 30° arc per cycle) and redesigned stir paddle were selected for the low shear requirements of the microgravity experiments. Conversion histories accurate to within 2% were obtained after apparatus modification and procedural changes were implemented.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 28 (1995), S. 2754-2764 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 28 (1995), S. 2765-2771 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 251 (1973), S. 241-250 
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Zusammenfassung Die Technik des Ultrazentrifugierens (1) wurde benutzt für eine Untersuchung des Einflusses von pH, emulgierenden Bestandteilen und Elektrolytgehalt auf die Minimumdrucke, die für eine Vereinigung von Styrol-Butadien-(60∶40) Latex, das mit stearinsaurer Seife stabilisiert ist, benötigt werden. Die Methode gibt ein Maß der Kraft, die einer Vereinigung von Latexteilchen entgegenwirkt, und diese Kraft ist quantitativ auf die primären Maxima in den Kurven Von Kraft gegen den Abstand der Teilchen bezogen entsprechend der DLVO-Theorie. Die Untersuchung läßt vermuten, daß die Stabilität dieses LatexSystems durch die abstoßende elektrostatische Kraft beherrscht wird. Sie wird durch Faktoren kontrolliert, die diese Kraft beeinflussen, insbesondere die Bedekkung der Teilchenoberfläche mit Ionen, die das Potential bestimmen, und die Dicke der Doppelschicht, die durch die Konzentration einwertiger Elektrolyte modifiziert wird.
    Notes: Summary The ultracentrifugation technique (1), was used to study the effect of pH and of emulsifier and electrolyte contents on the minimum pressures required to coalesce styrene-butadiene (60∶40) latex stabilized with stearate soap. The method provides a measure of the force opposing coalescence of the latex particles which correlates qualitatively with the primary maxima in the force-interparticle distance curves calculated according to DLVO theory. The study suggests that stability of this latex system is dominated by the electrostatic repulsive force and is controlled by factors influencing this force, specifically coverage of the particle surface with potential determining ions and the thickness of the double layer, as modified by the concentration of univalent electrolytes.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 1755-1767 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The grafting of methyl methacrylate (MMA) onto polybutadiene (PB) latexes prepared by seeded emulsion polymerization at 50°C was investigated as a function of: (a) initiator concentration used in the secondary polymerization, (b) monomer-to-polymer ratio, (c) the specific surface area of the seed latex, and (d) the degree of conversion. The thin layer chromatography/flame ionization detection (TLC/FID) technique was used to determine the proportion of graft copolymer in the core/shell latex, It was found that grafting PMMA onto PB depended upon the concentration of initiator, decreasing as the concentration was increased. The amount of grafting increased with increasing specific surface area of the seed latex, while the molecular weight of the acetone-soluble graft copolymer decreased. The amount of graft copolymer was found to decrease concurrently with increasing monomer-to-polymer ratio and degree of conversion. These results suggest a hydrogen abstraction mechanism in the formation of graft PB-PMMA through a chain transfer process.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 3569-3587 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new approach is presented to calculate both the distribution of particles with iradicals and the average number of radicals per particle in emulsion polymerizations carried out using oil-soluble initiators. The convergence and accuracy of the approach were examined. It was found that, in agreement with previously published experimental results, the present approach predicts a kinetic behavior similar to that found for water-soluble initiators. This effect is primarily due to the desorption of initiator radicals from the polymer particles rather than the contribution of the fraction of oil-soluble initiator dissolved in the aqueous phase.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 29 (1991), S. 857-867 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Monodisperse microscopic poly (methyl methacrylate)/polystyrene composite particles of 1-10 μm diameter were prepared by seeded emulsion polymerization of styrene in poly (methyl methacrylate) seed particles which were initially prepared by dispersion polymerization. The resulting composite particles were characterized by transmission and scanning electron microscopy. The unique morphology of the composite particles comprised three types of polystyrene domains embedded in a continuous poly (methyl methacrylate) matrix: the dispersed “internal” domains in the interior, the interconnected “subsurface” domains that from a crust beneath the surface, and the separated “surface” domains at the surface. In addition to thermodynamics and kinetics, the phase separation in composite particles is affected by polymerization mechanism. The complicated particle morphology found is attributed to the coexistence of bulk polymerization and emulsion polymerization (radical absorption and desorption) mechanisms. An explanation of the formation of the observed morphology is proposed. With varying poly (methyl methacrylate)/styrene ratio, the internal viscosity and the competition between the two polymerization mechanisms resulted in a series of interesting morphologies.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 245-256 
    ISSN: 0887-624X
    Keywords: microspheres, aggregation ; divinylbenzene, copolymerization ; seeded emulsion polymerization ; particle morphology ; gel, phase separation ; monodisperse macrospheres ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Monodisperse porous styrene-divinylbenzene copolymer particles were prepared via seeded emulsion polymerization using a mixture of linear polymer (polystyrene seed) and non-solvent as inert diluent. Experimental evidence was presented to describe the mechanism of formation of porous polymer particles during the copolymerization and solvent extraction stages, in which porosity was a consequence of phase separation in the presence of diluents. Pore structure formation was investigated by changes in copolymerization kinetics, gel content, crosslinking density, particle morphology, surface area, pore volume, and pore size distribution. The process of copolymerization was presented, based on the concepts of production, agglomeration, and fixation of the interior gel microspheres of polymer particles. A portion of linear polymer used as diluent was found to participate in the network structure while the porous matrix was built-up. The influence of the removal of the linear polymer from the matrix pores during the solvent extraction process on the porous structure was also discussed.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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