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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 1638-1648 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The A˜ 1A‘–X˜ 1A' band systems of HCOCN and DCOCN have been studied in depth using the technique of pyrolysis jet spectroscopy. Ab initio predictions of molecular structures and vibrational frequencies for the ground and excited state were made, to assist in the assignment of the vibronic structure in the laser-induced fluorescence (LIF) spectra. A resolved emission spectrum obtained by laser population of the 81 level of the excited state was analyzed to establish the ground state vibrational frequencies. Both the LIF and resolved emission spectra are consistent with a substantial elongation of the C=O bond on excitation, and smaller changes in the other geometric parameters. The excited state inertial defect, the pattern of bands involving the antisymmetric vibrations, and the ab initio predictions all suggest that the excited state structure is only slightly nonplanar. A rotational analysis of the 910 band of the DCOCN LIF spectrum has provided the first experimental rotational constants for the ground state of formyl cyanide-d1, which should be useful in attempts to observe the microwave spectrum. The uv spectrum of formyl cyanide is found to be remarkably similar to that of propynal.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 63 (1941), S. 2523-2524 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The rias of NW Spain are coastal ecosystems of high biological productivity and great economic importance. They are intensively exploited by man for fish and shellfish. There are a number of important centres of population and industrial activity along their margins, which serve as sources of contamination. In this context, it is desirable to achieve the best possible understanding of the physico-chemical processes that control spatial and temporal variations in the geochemical, mineralogical and sedimentological characteristics of near-surface sediments in the Ria de Pontevedra and, in particular, the distribution and mobility of heavy metal contaminants. Thus, adequate environmental planning can be achieved for this site and understanding gained for comparable contexts. Core samples were examined from the inner, middle and outer parts of the ria. Grain-size distributions reflect the presence of two main populations, one dominated by silt and clay, derived mainly from terrestrial sources, and the other by fine sand to coarse silt, which is derived mainly from continental shelf and ria mouth sources. Mineralogical analysis shows an abundance of terrestrial intensive-weathering products near the ria head, a dominance of shelf-derived sediment towards the mouth and the presence of several diagenetic minerals whose nature varies with location within the ria. In the inner ria, the near-surface sediments are slightly enriched in Pb, Cu and Zn from anthropogenic sources. These sediments are fine grained and have a high organic content; hence, they have a higher potential to sorb contaminants than the coarser grained, less organic-rich sediments of the mid and outer ria. The estimated sedimentation rates for the fine-grained organic-rich sediments from the inner part of the ria are about 1 mm year–1. The dominant authigenic minerals in the inner ria are iron sulphides, whereas in the mid and outer ria, iron silicates and oxyhydroxides are more important. These differences in authigenic iron mineralogy are clearly reflected by the magnetic properties of the sediments.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Many ancient early diagenetic siderite concretions are thought to have been precipitated by microbially-mediated reactions, and their trace element chemistry has been used to infer palaeoenvironments of formation (e.g. marine versus freshwater). In this study, pure cultures of the microorganism Geobacter metallireducens were used to precipitate siderite in the laboratory at a range of temperatures (18–40°C). Magnesium and calcium, in three different ratios (3:1, as in seawater, 1:1, and 1:3 as in freshwater), or manganese were added to some cultures at each incubation temperature to study trace element incorporation. The siderite produced exhibited the rhombohedral crystal form typical of concretionary siderite. However, this microbial siderite did not simply retain the trace element chemistry of the water from which it precipitated, as is assumed in palaeoenvironmental interpretations. Instead, manganese and calcium incorporation were found to be inversely proportional to the rate of microbial activity, which itself is dependent upon the nutritional status of the microorganisms. Magnesium incorporation was found to be rate-independent, and at high Mg/Ca ratios, it caused inhibition of calcium incorporation. In short, the influence of microorganisms on the trace element composition of early diagenetic siderite must be taken into account in order to produce valid palaeoenvironmental interpretations.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Australasian journal of dermatology 23 (1982), S. 0 
    ISSN: 1440-0960
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: A rare benign skin tumour with the histology of an epithelioid leiomyoma is described in an eight-year-old boy. Some comments on malignant varieties are mentioned.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 17 (1877), S. 62-62 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] CAPT. TUCKEY is dead and gone and cannot answer for himself; it may therefore, perhaps, serve to clear his memory in some measure of a doubt about the correctness of his description of the Yallala Rapids in 1816, arising from the very different account of them given by Stanley sixty years ...
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0378-1119
    Keywords: HBV ; Recombinant DNA ; immunoglobulin ; mouse ; polymerase chain reaction
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 27 (1883), S. 337-337 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] IN the letters on the above subject that have appeared in some recent numbers of NATURE, the writers lead us to believe that a current of air is necessary to enable a bird to “hover” or retain when on wing a motionless position. My observations lead to an opposite conclusion, as I have often ...
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 27 (1883), S. 366-366 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] ON reading the letter of W. Steadman Aldis in NATURE (voL xxvii. p. 338) yesterday, I was reminded by a person present that some years ago, when in Orkney, I pointed out an appearance that most people unaccustomed to witness it might have taken for a great sea-monster. This was no hing more or ...
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 27 (1883), S. 366-366 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] IN his letter in NATURE, vol. xxvii. p. 337, Mr. J. Birmingham does not mention what kind of bear it is that throws down pieces of rock “in order to catch the bareins,” as told by the Kamtschadales; but the Eskimos have a somewhat similar story of the white bear, when attacking the walrus, the ...
    Type of Medium: Electronic Resource
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