ISSN:
1862-0760
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Physik
Notizen:
Abstract The conductivity of Nafion, especially as a function of water content, represents an important parameter for its applications as membrane in electrochemical devices. All Nafion types (105, 112, 115 and 117) exhibit a favourite swelling direction, most probably the strain direction. For this direction Nafion 115 and 117 exhibit an increment up to 30 % higher than the other planar dimension. Conductance (ohm−1) data obtained by impedance measurements along the three dimensions of the Nafion membranes do not show any remarkable anisotropy. Along all the directions, an activation energy of about 130 meV for the proton transport is found for all types of Nafion, after swelling. In the longitudinal geometry, the activation energy of the conductance has been investigated in the temperature range 300–350 K as a function of relative humidity of the environment, which affects the membrane water content. The conductance and its activation energy has been found increasing by decreasing water content. This effect is, however, more pronounced for Nafion 117 than for Nafion 105.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF02375802
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