ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Allylic phosphine systems were studied as phosphorus-carbon double bond precursors. 1-Phenyl and 1-butyl-1-phospha-1,3-dienes were generated by pyrolysis at 350-460°C of the corresponding diallyl phosphines in a stirred-flow reactor. The unsubstituted phosphadienes generated in this manner dimerized; the formation of [4 + 2] cycloaddition products was confirmed by NMR and mass spectroscopic analysis. 31P NMR data of the 1-phospha-1,3-dienes were obtained.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hc.520020607
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