ISSN:
1572-9605
Schlagwort(e):
NQR in YBCO
;
AFNMR in YBCO
;
magnetic transition in hydrided 123
;
magnetic transition in hydrided 124
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Elektrotechnik, Elektronik, Nachrichtentechnik
,
Physik
Notizen:
Abstract The transition from superconducting to antiferromagnetic behavior in RE Ba2Cu3O7Hx, RE=Y, Gd, has been studied by Cu NMR and NQR. In the Gd compounds the spectra of Cu(1) and Cu(2) sites could be separated by the strong relaxation induced by the magnetic moments of Gd on the neighboring Cu(2) sites. Already at smallx of about 0.4, antiferromagnetic Cu(2) sites are revealed by an AF-NMR spectrum. At the samex we find a strong broadening of the normal NQR spectrum and a new sharp line at 27 MHz for63Cu, indicating a new EFG of the Cu(1) sites in the AF phase. The transformation to the AF state is complete at aboutx=2.0. Annealing of the doped material at 350 °C leads to the normal oxygen-depleted 123 compounds, proving that the cation lattice is not distorted even at highx. As in the case of the pure YBCO, no static magnetic moments exist at the Cu(1) sites of the hydrogen-containing phase. Hydrogen addition is found to produce a similar antiferromagnetic spectrum in 124 material.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF01320872
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