ISSN:
0009-2940
Keywords:
Oxidation by HOF
;
Hypofluorous acid
;
Addition compounds of HOF and HF with acetonitrile
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Oxidation Reactions with HOF and Adducts of HOF and HF with AcetonitrileIn acetonitrile solution HOF oxides CF3SSCF3 via CF3S(O)nSCF3 (n = 1, 2) to yield [CF3S(O)2]2O. Analogously, CF3Se(O)OH and CF3SeX (X = Cl, Br) are oxidized via CF3Se(VI) intermediates to provide finally [CF3Se(O)2]2O. With CH3CN at low temperatures HOF and HF form 1:1 adducts, whose structures have been elucidated by low-temperature X-ray structure analysis. Additional proof for the formation of CH3CN · HF in the liquid phase is provided.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941271009
Permalink