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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 18 (1985), S. 695-699 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 13 (1974), S. 391-396 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 600-608 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new method of instrumentation for normal-stress determinations was developed, making possible accurate unsteady state as well as steady state measurements, eliminating errors arising from fluid-filled pressure-tap holes, and permitting the determination of the complete stress state in a single cone-and-plate shearing-geometry experiment. Sensitive, nonflow semiconductor pressure transducers mounted at several radial positions with their pressuresensing diaphragms flush with the plate surface provide data for the normal-stress distribution. The normal-stress distribution, together with the total normal force from the single-geometry experiment, enables determination of the primary and secondary normal-stress differences by two independent methods of analysis while the transmitted torque enables determination of the viscosity, each as a function of shear rate. Only the normal-stress distribution is required if an independent check on the normal-stress determination is not desired. Similar advantages arise in the application of the instrumentation to a parallel-plate shearing geometry, The new instrumentation was used in the determination of the complete rheological stress state of three aqueous and two “Tetralin” solutions of polymers in a cone-and-plate shearing geometry shear rates of 0.02 to 450 s-1 on a Model R-17 Weissenberg Rheogoniometer. The normalstress differences computed by means of two methods of analysis are in surprisingly good agreement. The ratio of the secondary to the primary normal-stress difference was negative. The absolute values of this ratio decreased with increases in the shear rate, the maximum observed value being 0.4.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 713-720 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Temperature and velocity profiles and pressure losses were computed for laminar, temperature-dependent Newtonian flow from a stream tube through an abrupt contraction into and through the entrance region of a smaller coaxial tube, in which the fluid was cooled or heated at constant wall temperature. The equations of motion and energy, including axial diffusion and viscous dissipation, were solved numerically for diameter ratios of one and two, a practical temperature range, and NPe and NRe up to 100. Entrance temperatures and velocities are far from uniform, and pressure losses are greater than those computed using simplified equations and uniform entrance temperatures and velocities.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 1 (1955), S. 544-548 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is presented for determining the flow-rate - pressure-gradient relationship for the streamline flow of the large class of non-Newtonian, nonthixotropic fluids to which the Powell-Eyring equation applies. The general procedure and assumptions required in developing this method are the same as used in deriving the Hagen-Poiseuille equation except that the Powell-Eyring equation is used in place of Newton's equation to relate shear stress to shear rate.The method can be used to predict pipe-flow pressure gradients from both precision viscometer data and pipe-flow data. Its applicability is demonstrated for three typical non-Newtonian fluids, 3% carboxymethylcellulose in water, 15% napalm in kerosene, and 33% hydrated lime in water.When used with pipe-flow data, it resembles the method of Alves and associates, compensating for the inconvenience of an additional step in calculation procedure by providing a means of extrapolating beyond the range of the experimental data.The relationships developed facilitate the application of shear-stress - shear-rate data in the design of conduits for non-Newtonian fluids.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 467-471 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ryan and Johnson's treatment of the transition from laminar to turbulent flow is extended to include the heated flow of pseudoplastic liquids in smooth tubes. A limitation is pointed out for the case of Bingham plastic fluids.The theoretical results of the present investigation are compared with experimental data obtained for a large number of pseudoplastic fluids having widely variant rheological properties. It is found that the theoretically predicted flow rates corresponding to the inception of turbulence agree with the observed values to within ±6.7%. The theoretical critical wall shear stresses agree within ±3.87% with experiment.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 1196-1202 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Numerical solutions of the equations of motion and energy for the heating of non-Newtonian fluids in rectilinear, axisymmetric laminar flow in tubes of circular cross section are extended to the case of cooling at constant tube-wall temperature. The fluid density, heat capacity, and thermal conductivity are assumed constant, but the flow properties are represented by the temperature-dependent equation τ = m(Ṡ exp ΔH
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 1621-1631 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimentally determined viscosities, first and second normal stress differences, and compliances for concentrated solutions of linear and four-arm star-branched polystyrenes and polybutadienes depend on the shear rate and the molecular weight, in agreement with theory and previously reported experimental results. The ratios of the second to first normal stress difference are -0.29 and -0.214 for the linear and branched polymers, respectively, independent of molecular weight, molecular weight distribution, concentration, and shear rate.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 154-160 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simple temperature dependent equation τ = K [Ṡ exp(ΔH
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 145-151 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Terminal velocity drag coefficients CD were determined for cylinders, prisms, disks, and spheres in air and water at NRe from 1,000 to 300,000, the regime where particles rotate and/or oscillate. These and other similar data show that CD is a function of particle and fluid densities ρp and ρf, as well as shape and NRe.By considering CD a function of particle moment of inertia and the rotational moment generated by circulation (or alternatively the field force and the lift), one can deduce that \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm C}_{\rm D} = {\rm f}\left({\frac{{\rho {\rm p}}}{{\rho {\rm p}}}\,{\rm or}\,\frac{{\rho {\rm p} - \rho {\rm f}}}{{\rho {\rm f}}},\hbox{a length ratio, N}_{{\rm RE}}} \right) $\end{document}. This relationship correlates the data for ρp = 1.2 to 8.3 and ρf = 0.1 to 1.3 g./cc. to within ± 10%.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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