ISSN:
0538-8066
Schlagwort(e):
Chemistry
;
Physical Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The bond dissociation energies of tetramethyl germane, triethyl stibine, tetraethyl lead, and triethylphosphine were determined using the technique of very-low-pressure pyrolysis. Arguments are presented for log A ≥ 17.0. The respective dissociation energies ΔH298 are 83, 57, 54, and 68 (±2) kcal/mol. A consistent set of methyl bond energies to main group metals is determined from these and previous results, and is examined for trends. Bond energies for various radicals to tin are also derived.
Zusätzliches Material:
4 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/kin.550150207
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