Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
112 (2000), S. 2790-2797
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
We have computed all the electronic states of ClO arising from the Cl(2P)+O(3P) dissociation limit and several of those connected with Cl(2P)+O(1D). Only two excited states have attractive potentials, A 2Π and 1 4Σ−. The A 2Π state undergoes a well known predissociation, because several as yet unknown potential curves cross the A 2Π one and are coupled to it by nonadiabatic and/or spin-orbit interactions. The calculation of the interaction matrix elements allows to explain the predissociation of A 2Π, due to transitions to the 3 2Π, 12Δ, 2 4Σ− and other less important states, all leading to the Cl(2P)+O(3P) dissociation. © 2000 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.480853
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