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  • 1995-1999  (51)
  • 1980-1984  (784)
  • 1998  (51)
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  • Chemical Engineering  (574)
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  • 1995-1999  (51)
  • 1980-1984  (784)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Space science reviews 84 (1998), S. 199-206 
    ISSN: 1572-9672
    Keywords: Nuclear reactions ; Nucleosynthesis ; Abundances ; Stars:Evolution ; Interior ; Rotation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We first recall the observational and theoretical facts that constitute the so-called 3He problem. We then review the chemical anomalies that could be related to the destruction of 3He in red giants stars. We show how a simple consistent mechanism can lead to the destruction of 3He in low mass stars and simultaneously account for the low 12C/13C ratios and low lithium abundances observed in giant stars of different populations. This process should both naturally account for the recent measurements of 3He/H in galactic HII regions and allow for high values of 3He observed in some planetary nebulae. We propose a simple statistical estimation of the fraction of stars that may be affected by this process.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 61-67 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Risk assessments have been performed to determine the risk associated with the transportation of hazardous wastes through a city. In the course of these assessments, a number of modeling issues arose relating to transportation accident rates, the characterization of incidents, the effect of thermal radiation, the impact of exposure to toxic chemicals, and the threshold for acceptable risk. This paper discusses these issues.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. S3 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 98-103 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper presents the design of ribbon wound pressure vessels useful for Ammonia, Urea and Methanol plants. The design is to create a thin shell of 1/5 the total wall thickness required, weld it to the end pieces, and wind 4 to 8 mm thick ribbons of 80 mm width at an angle of 15 to 30 degrees on the inner shell, using a prestress. The ribbons are welded at the ends and an even number of layers are wound cross-helically on to the shell. With more than 7000 vessels over the pressure range of 50 to 350 atmospheres in use in the various chemical industries in China over the past 30 years, their safety record has been excellent. Of particular interest has been the application of this technology in the Ammonia and Urea plants, where the design allows fabrication of these vessels at substantial reduction in cost, and early delivery, when compared to the mono wall technology.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 20-22 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Most audits try to look at a representative selection of the plant procedures and equipment. An alternative is a survey, a look in depth at selected procedures (such as those for testing alarms and trips, issuing permits-to-work, controlling modifications, taking samples or testing relief devices) or selected equipment (such as level glasses or equipment for handling LPG). If the procedure or equipment is well-chosen, surveys may make a bigger contribution to safety, per person-hour, than a conventional audit.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 39-42 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Under OSHA 1910.119, all Process Safety Management (PSM) facilities are required to keep their pressure relief system design information current. This article demonstrates why a pressure relief system design verification effort must be based on an equipment list, rather than a relief device list, in order to ensure that every piece of equipment is adequately protected. The formerly common practice of simply checking the design bases of all existing relief devices is deficient is deficient since this technique does not systematically ensure that every piece of equipment is protected.The “Berwanger Method” is a step by step process for designing or analyzing a pressure relief system to meet OSHA 1910.119 Process Safety Information (PSI) and Process Hazard Analysis (PHA) mandates. The method uses a relational database which tracks the relationships between protected equipment, potential overpressure scenarios, and protective devices.The challenge facing an operating company does not end once the design basis has been “verified” - the design basis information must also be maintained and be readily accessible to avoid costly reinvention of the wheel down the road. The “Berwanger Method” also addresses these maintenance issues.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 49-60 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper reports on a comprehensive literature search and small scale experimental work on the reaction characteristics of phosphorous trichloride and water. More than 30 tests were conducted, including both closed and open test cells. The water to phosphorus trichloride molar ratio was varied from 1 to 25. When in contact, water and phosphorus trichloride will form two liquid layers with a reaction starting at the interface. The impact of variables on reaction rates including the interface surface area, layer depth, and stirring were investigated experimentally. A reaction rate model that fits all the measured data is presented. Case studies illustrating the use of this data for emergency relief systems and vent containment design are presented in reference. [1].
    Additional Material: 10 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 68-73 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two major accidents in the 80's: the summit Tunnel Fire, England and Piper Alpha disaster, an offshore platform in the North Sea; and very recently, possible explosion of the Boeing, TWA flight 800 at New York, makes it imperative that further research into the mechonisms of the ignition of flammable vapor/air mixture in contact with hot surfaces needs to be done. There have been a number of studies of ignition by hot surfaces, but in all these studies the ignition sources were wire, sphere or strip, i.e., most of them were flat surfaces. But to the authors' knowledge, other variables which affect the ignition mechanism such as irregular geometrical shapes have not been studied. The purpose of this paper is to examine how the degree of confinement (or, configuration), size and orientation, of the heated surface affects the ignition temperature of the flammable vapors. The results were obtained by experimentnal and by computational fluid dynamics.
    Additional Material: 13 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. S3 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 9-15 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The design and deflagration pressure relief vents is based on correlations developed for various types of combustible materials and for enclosures of different strengths. The primary guideline for deflagration vent design in the US is NFPA 68 Guide for Venting of Deflagrations [5]. That document gives guidance for the design of vents for enclosures containing flammable gases, specifically hydrogen, coke oven gas, propane, and methane. Application of the guide to other gases is achieved using the KG value. Values of KG are published for a relatively small number of gases, as seen in Table D-1 of NFPA 68. This work present KG data on several additional gases obtained in a laboratory scale test vessel along with analysis of the results with respect to published values of fundamental burning velocity.
    Additional Material: 9 Ill.
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  • 11
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 23-31 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In May 1996, the Flammable and Combustible Liquids Code Committee of the National Fire Protection Association (NFPA) proposed for adoption by the Association a new edition of NFPA 30, Flammable and Combustible Liquids Code. This new edition was the culmination of two and one-half years' work by the Committee and included one of the most significant changes to that document in some twenty years: the incorporation of mandatory fire protection criteria for warehouses and other inside areas that store flammable and combustible liquids in containers and portable tanks.
    Additional Material: 2 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 32-38 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes the development of a risk ranked Inspection Recommendation procedure that is used by one of Exxon's chemical plants to prioritize repairs that have been identified during equipment inspection.As part of the Company's Safety Management Practices initiative in the late 1980's a procedure was put into place to ensure that an Inspector's repair recommendations were properly addressed by the organization. The initial procedures were successful at “systematizing” the documentation and stewardship-to-completion of the Inspector's recommendation, however, there were complications with the original process: (1)The Inspector made a simple High, Medium or Low assessment of the priority/criticality of the recommendation. Frequently, this resulted in disagreements with Operations about the true priority of the recommendation.(2)If there was agreement on the priority of the recommendation, there was still disagreement on the relative rank within the priority-which high priority was the highest priority?(3)With limited funds to spend on repairs, it was (and is) important to make sure that the money was being spent on the highest risk items that had the greatest risk reduction/cost benefit ratio.To address these concerns, the procedure was modified to incorporate a risk assessment of the recommendation by both the Inspector and Operations. In the new procedure, the Inspector describes the deficiency that he/she finds and assesses the probability of failure within a certain time-frame. Operations must assess the consequences, from an environmental, safety and economics standpoint, were the failure to occur. These assessments are combined in the typical risk equation (risk = probability × consequences) to arrive at a severity index which serves to rank the recommendation relative to the other recommendations. Because Operations participates in the assessment there is very little disagreement about the priority of the recommendation. The severity index puts the recommendations in order so it is quite clear which are the highest priority recommendations. This process has helped to focus the entire organization on those deficiencies that represent the greatest risk with the result that less time and money is spent correcting items that have a low risk/cost benefit ratio, allowing these savings to be used to reduce the higher risks in the plant.
    Additional Material: 4 Ill.
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  • 13
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 124-126 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simple analytical method is presented for estimating the hybrid minimum ignition energy (HMIE) of dust-gas mixtures, based on the assumed generality of Bartknecht's well-known test data for mixtures of propane with a series of dusts in air. Since the HMIE equation requires input data which might be unavailable, the use of conservative default methods is discussed.
    Additional Material: 1 Ill.
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  • 14
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 138-148 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A large and potentially hazardous decrease in aldehyde autoignition temperature (AIT) occurs with increased pressure. The AIT-pressure curve determined in a 5 L stainless steel sphere was similar for propionaldehyde and butyraldehyde in air, falling from about 185°C at atmospheric pressure to 90°C at 140 psia. Reduction of oxygen concentration had little effect on propionaldehyde AIT. At 100°C and 140 psia, autoignitions accompanied by at least a doubling of pressure were observed above 4% oxygen. In the presence of a few grams of free liquid, propionaldehyde vapor ignited in air at initial conditions significantly below the AIT. The mechanism appears to involve rapid Fe-catalyzed exothermic liquid-phase oxidation leading to autoignition of the adjacent heated gas layer. An acetaldehyde vapor-air mixture in the presence of free liquid and rust exploded at room temperature when air pressure was increased to 95 psia; this result is discussed with reference to a cylinder overpressurization that occurred while making up an ostensibly sub-LFL calibration mixture with compressed air. Propionaldehyde's limiting oxygen concentration (LOC) was investigated in the near-autoignition region using the same 5L apparatus; the findings are discussed with reference to an overpressurization incident in an air-liquid partial oxidation reactor. The general results are used to illustrate the application of LOC in partial oxidation processes subject to autoignition and to discuss elements of the current ASTM draft test method for LOC, which does not address test difficulties associated with condensable and/or reactive gas systems.
    Additional Material: 16 Ill.
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  • 15
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. F3 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 157-170 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Risk analysis in chemical process industries is an elaborate exercise involving several steps from preliminary hazard identification to development of credible accident scenarios, to preparation of strategies for prevention or control of damage.All this requires substantial inputs of time and money. In order to get an approximate yet workable assessment of risk at much lesser costs, indices have been developed which link typical findings of elaborate risk analysis to scales of risk. The scales, in turn, provide workable measures of hazards/risks/safety.In the past, indices have been reported for swift risk assessment - the noteworthy among them include Dow fire and explosion index, Mond fire, explosion and toxicity index, IFAL index, and mortality index. A few rapid ranking techniques have also been proposed.This paper presents a new system of methodologies for Hazard Identification and Ranking (HIRA). The system consists of two indices: one for fire and explosion hazards and another for the hazard due to likely release of toxic chemical. The magnitudes of these indices indicate the severity of the likely accident; in terms of the size of the impacted area.HIRA has been applied to a typical chemical process industry - a sulfolane plant - and its performance has been compared with that of the Dow's and the Mond's indices. The study reveals that HIRA is more sensitive and accurate than the other indices.
    Additional Material: 12 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 200-208 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 14 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 213-218 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: On October 31, 1987 a crane lifting a heat exchanger convection section failed and severed a 4″ loading line and a 2″ pressure relief line to an HF alkylation reactor settler drum at a petroleum refinery in Texas City, Texas. Vapors were emitted under pressure for about two hours and the vessel was plugged and drained aproximately 44 hours later. A plume from this accidental release passed through residential areas, damaging some vegetation (brown lawns), and spawning a class action law suit. An extensive analysis was conducted to determine the total inventory loss and to model the blowdown process and the concentrations of HF in the plume. Since the discharge rate was decreasing with time, a peak concentration of HF in the emitted vapors occurred just before the water spray mitigation system became fully operative. Consequently, the mitigation efforts were more effective late in the response when concentrations were already low. The predicted plume concentrations are consistent with observed vegetation damage effects, with concentrations below Emergency Response Planning Guideline Level 3 past 3/4 mile from the source. These results support a policy of sheltering in place during such an event.
    Additional Material: 8 Ill.
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  • 19
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A fifty-five gallon steel drum of a liquid organic peroxide pressurized and ruptured in the mix room of a manufacturing plant. The head of the drum blew off and the ejected material ignited. The resulting fire was extinguished by the building sprinkler system and operating personnel. Although there were no injuries, the fire caused significant damage in the mix room. The investigation of this incident, its likely cause, and the corrective actions will be discussed.
    Additional Material: 9 Ill.
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  • 20
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 238-242 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Brazoria County Petrochemical Council, 13 companies that are working together to enhance relations between industry and the community, united in a joint effort at complying with the EPA's Risk Management Program. One of the significant issues the group had to address was the need to develop meaningful hazard assessment for presentation to the public. The EPA's “Table Look-Up Approach” found in the Offsite Consequence Analysis Guidance document is certainly a good tool; however, the built-in conservatism results in over-estimates of potential hazard areas. Much more meaningful results are shown to be obtained using one of the hazard release models.The value of using a credible scenario with realistic meteorological data is demonstrated through the consistently smaller areas predicted by the PHAST Model for planning purposes. Realistic scenarios/failure modes and realistic model parameters are important so that the risk to the public is not overstated. Proprietary models such as PHAST are invaluable in providing more meaningful consequences for planning purposes.
    Additional Material: 2 Tab.
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  • 21
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 263-271 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Some of the hazards encountered by process plant operators involve the operation of in-line valves to control, start, and to stop flow. Torque required to operate valves may vary according to valve wheel size, in-line pressure, and valve flange position (open/closed). This study determined how valve wheel size, in-line pressure and valve position (open/closed) affect torque required to actuate a valve. Data were gathered with each combination of size, pressure and position for 336 valves in an operating petrochemical process facility. The results indicate that the main effects of valve wheel size, the in-line pressure, and open/closed valve position significantly affect operational torque requirements. In addition, the interaction between position and pressure was significant for operational torque. The implication of these results is that operators are exposed to operational torque requirements that exceed maximum acceptable capabilities that have been determined in previous studies.
    Additional Material: 12 Ill.
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  • 22
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 288-296 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An ammonia storage tank was built at the BASF Antwerp site in 1969 on land reclaimed from the sea. After several years of operation uneven foundation settlement, of up 2, occurred. In order to assure stability of this area for the next operation period (at least 10 years) measures were taken to ensure continued safe operation. One key measure was strain gauge monitoring at the location of maximum stress.
    Additional Material: 19 Ill.
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  • 23
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 297-301 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Baker-Strehlow methodology was developed to provide an objective approach to prediction of blast pressures from vapor cloud explosions. The complete methodology was first published in 1994 [1]. Since then, it has evolved through ongoing research and use in VCE hazard analyses, facility siting studies and accident investigations. This article gives a brief overview of a paper on recent developments in the Baker-Strehlow methodology presented at the 31st Loss Prevention Symposium in Houston on March 9-13, 1997. Because the entire paper is too lengthy to be presented here, the following discussions may be lacking in some details. A copy of the complete paper can be obtained from the American Institute of Chemical Engineers (AIChE).Since the Baker-Strehlow method was first published, it has been used extensively in VCE hazard assessments in refineries and chemical plants. As expected, many practical lessons have been learned during the course of the hazard assessments, and the Baker-Strehlow method has evolved as a result. The changes have been evolutionary, not revolutionary. In keeping with the goals of the original study in which the methodology was developed, all changes have been incorporated with the intent of achieving an objective methodology to provide consistent prediction of VCE blast effects.The revisions to the Baker-Strehlow method resulting from experience gained during plant walk-downs and hazard assessments include: Systematic identification of “potential explosion sites” or “PESs,”Selection of the level of confinement for mixed zones of 2D and 3D confinement,Deciding on flame expansion when confinement is elevated above the vapor cloud,Selecting the reactivity for a fuel that is a mixture of fuels with differing reactivities,Predicting blast loads when there are multiple PES's within a vapor cloud considering different ignition source locations.
    Additional Material: 4 Ill.
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  • 24
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 83-85 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Safety, health and loss prevention are major areas of interst for the American Institute of Chemical Engineers (AIChE). There has been an evolution of these concerns over the years in the Institute just as it has in industry. This article chronicles this evolution.
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  • 25
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998) 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 26
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 1-8 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Recent guidelines released by the U.S. EPA define a worst-case scenario as a release under stable atmospheric conditions defined as Pasquil-Gifford stability class F. Unfortunately, very few tests at F stability have been available heretofore to provide a basis for models. Recent test data with propane releases by the German research organization TUV provide a set of 60 experiments conducted specifically to define the effects of atmospheric stability class on dispersion. Of these, 25 tests were at F stability. A comparable number were at each other stability class A through E. In addition 23 tests were at wind speeds under 1.5 m/s in stable atmospheres. This paper reports on adjustments made to our models based on these new data by reducing the originally-postulated sensitivity to stability class. In spite of considerable scatter in the TUV data, particularly between two different types of propane analyzers, the model allows us to extract information by averaging over the tests.
    Additional Material: 15 Ill.
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  • 27
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 16-19 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A multi-disciplinary team developed a guideline for determining access restriction zones around vented solids handling equipment. The guideline provides a method for ensuring the discharge from a vented explosion will not cause injury to personnel. The steps in this method include: calculating the extent of external hazards from vented explosions; identifying potential areas where personnel could be exposed to a hazard; identifying ways to eliminate or reduce the hazard area; and establishing and documenting any access restrictions needed. Hazard zone calculations use the latest knowledge from research into fireball size, flame length and external pressure equations in VDI 3673. The guideline provides guidance for using this information. Options for mitigating or reducing external hazards from vented explosions are also described. As part of the project, the team audited several solids handling systems to look for potential oversights in existing restricted access areas. Some of the team's learnings from these audits are reviewed.
    Additional Material: 2 Ill.
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  • 28
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    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 17 (1998), S. 43-48 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper defines situation awareness (SA) and discusses its importance to operator-machine system safety and functioning in the context of process control activities. Specifically, identified are relationships of human detection of critical process cues converying the status of automated control systems and operator interpretation of the meaning and relevance of such information to the potential for negative incidents in chemical processing. Beyond individual operator SA in interacting with control systems, intra- and inter- work team SA are discussed for supporting individual attainment of process control responsibilities. Factors critical to team SA are discussed. “Road blocks” to team SA are also analytically examined. Lastly, methods for assessing individual and team SA are reviewed and vehicles for relating outcomes of these methods to changes in process control operator and team behavior to improve human-machine system safety and performance are relayed.
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  • 29
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    Process Safety Progress 17 (1998) 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 30
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    Process Safety Progress 17 (1998), S. 74-81 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The knowledge of the ingition behavior of dust-air mixtures due to electrical sparks (MIE, Minimum Ignition Energy) and hot surfaces (MIT, Minimum Ignition Temperature) is important for risk assessments in chemical production plants. The ignition behavior determines the extent and hence the cost of preventive protection measures.This paper describes the use of the minimum ignition energy and minimum ignition temperature as very important safety indexes in practice.Based on the latest results from large scale experiments on pneumatic filling of silos with polymeric materials and new results of full scale filling tests using Flexible Intermediate Bulk Containers (FIBC) manufactured from a variety of materials, guidance can be given to ensure safe operation in different situations such as filling, emptying operations, type of powder handled.The aim of this paper is to assist people dealing with product. It reflects the present state of the art and current knowledge of the assessment and measures associated with powder handling.
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  • 31
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    Process Safety Progress 17 (1998), S. 104-106 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In mid-1997, an Advanced Process Control (APC) scheme was implemented at a resins manufacturing complex with the goal of minimizing flare fuel gas usage while maintaining sufficient energy (BTU/SCF flare gas) to be in environmental regulatory compliance. Prior to APC implementation, the flare system was manually controlled by plant operators with minor attention paid to the minimization of fuel gas usage. Since implementation, APC has saved the plant thousands of dollars in fuel gas costs and reduced unnecessary combusted fuel gas emissions.Hazard analysis techniques were used in the development of the control scheme. An overview of the APC used, the economic evaluation, and the hazard analysis techniques used in the project are presented here.
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  • 32
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    Process Safety Progress 17 (1998), S. 107-123 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the risk assessment parlance, especially with reference to chemical process industries, the term “domino effect” is used to denote “chain of accidents,” or situations when a fire/explosion/missile/toxic load generated by an accident in one unit in an industry causes secondary and higher order accidents in other units. The multi-accident catastrophe which occurred in a refinery at Vishakhapatnam, India, on September 14, 1997, claiming 60 lives and causing damages to property worth over Rs 600 million, is the most recent example of the damage potential of domino effect.But, even as the domino effect has been documented since 1947, very little attention has been paid towards modeling this phenomena. In this paper we have provided a conceptual framework based on sets of appropriate models to forecast domino effects, and assess their likely magnitudes and adverse impacts, while conducting risk assessment in a chemical process industry. The utilizability of the framework has been illustrated with a case study.
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  • 33
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    Process Safety Progress 17 (1998) 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 34
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    Process Safety Progress 17 (1998), S. 149-154 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This article deals with fire protection for water miscible flammable liquids stored in plastic containers packaged in boxes located on pallets. A series of fire tests was conducted with palletized rack storage arrangements using in-rack sprinkler protection at various levels. The intent of the paper is to present data from this test series for these types of commodities. The paper will identify various existing water miscible flammable liquid products stored in this fashion and provide background information for protecting this type of storage as it relates to NFPA 30 Flammable and Combustible Liquids Code. The test data indicates that further research work is needed in the area of plastic containers for use with the storage of combustible and flammable liquids. Included in the paper are discussions concerning possible protection strategies and suggestions for future research which would benefit those involved in risk management of this type of commodity.
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  • 35
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    Process Safety Progress 17 (1998), S. 176-183 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The safest method to prevent fires and explosions of flammable mixtures in the first place. This method requires detailed knowledge of the flammability region as a function of the fuel, oxygen, and nitrogen concentrations. A triangular flammability diagram is the most useful tool to display the flammability region, and to determine if a flammable mixture is present during plant operations.This paper describes how to draw and use a flammability diagram. A procedure to estimate the flammability region using the available and sometimes limited data is discussed. The paper also shows how to use the flammability diagram with plant operations involving inerting and purging, and from bringing vessels into and out of service. A compilation of flammability diagrams for 30 materials, based on previously published data is provided.An automated apparatus for acquiring data for a flammability diagram is described. The apparatus consists of a 20-L sphere with an automated gas mixing system, a fuse-wire ignition system, and a high speed pressure measurement and data acquisition system. Data derived from the apparatus includes flammability limits, maximum pressure during combustion, and the maximum pressure rate. The effect of fuse-wire ignitor dynamics on the results is studied. A flammability diagram for methane drawn from data obtained from the apparatus, is presented.
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  • 36
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    Process Safety Progress 17 (1998), S. 86-97 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Regulatory issues related to material safety have made the accurate measurement and/or prediction of flash points essential. The flash point is one of the major physical properties used to determine the fire and explosion hazards of a liquid. Flash points are used by virtually all governmental entities worldwide to define “flammable” and “combustible” materials for shipping and safety regulations.A model is described here for the calculation of closed cup flash points for multicomponent, single liquid phase, mixtures. The model is based upon rigorous vapor/liquid equilibrium calculations supplemented with information about the lower flammable limits (LFL's) and heats of combustion (ΔHc's) for the mixture's constituent components. The closed cup flash points predicted with this model are typically within ± 5°C of the experimentally reported values. Such a model is useful as a means of verifying experimental data and as a tool for screening product formulations prior to experimental flash point determination. The model should considerably enhance the safety evaluation portion of the product development cycle, thus leading to shortened product time-to-market cycles. While flash points calculated with this model are in excellent agreement with experiment, experimental determination is still encouraged for critìcal safety applications.
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  • 37
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    Process Safety Progress 17 (1998), S. 134-137 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: National Advisory Committee's Acute Exposure Guideline Levels (AEGLs) for ammonia are critically evaluated. The technical bases for concern about AEGL-2 and AEGL-3 values derived by the committee are summarized recommendations made.
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    Process Safety Progress 17 (1998), S. 127-133 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An explosion and flash fire in a fixed bed reactor occurred at a municipal wastewater treatment plant (WWTP). Two employees were injured in the accident. The accident occurred in an ozone treatment building where ozone was used to treat odors from the offgas of the sludge concentration units. Excess ozone manually was routed to the fixed bed reactor (ozone destruct unit) where the ozone is catalytically transformed into oxygen before being discharged to the atmosphere.An investigation of the accident was conducted to determine the root cause of the explosion and flash fire and identify corrective actions which the WWTP management could undertake to prevent a recurrence. This investigation included site inspections, interview with the injured employees, sampling and analysis of various materials, an explosion dynamics analysis, and a root cause analysis.It was concluded that cooling oil from one of the ozone generation units entered the main ozone gas line due to a crack in one of the reactor's dielectric tubes. The cooling oil was vented into the ozone destruct unit when an employee opened a ball valve on the main ozone gas line. The cooling oil, essentially a saturated hydrocarbon mixture, reacted exothermically when it contacted the manganese dioxide catalyst. The exothermic reaction resulted in an explosion which propelled the access panel outwards and dispersed the catalyst pellets. A flash fire followed the explosion. The flash fire burned two employees and caused thermal damage to a nearby control panel.Although this accident was the first of its kind at this facility, this was not the first time that the ozone generator had experienced a failure of a dielectric tube. Thus, there was a significant probability that a dielectric tube failure could leak cooling oil into the main ozone gas line. This failure event could, in turn, result in another explosion and flash fire. The WWTP staff neither designed nor fabricated the ozone generator-destructor system. Therefore, it did not seem appropriate for the WWTP staff to modify the ozone system. Instead, it was recommended that the ozone destruct unit be taken out of service. The WWTP management acted on this recommendation.
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    Process Safety Progress 17 (1998), S. 171-175 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An explosion occurred in a petroleum product storage tank at a refinery. The liquid petroleum product was a heavy oil used as an asphalt extender. There were no injuries, but the cleanup was costly. The storage tank was one of several which received the product stream from a dehydration unit. The accident occurred shortly after the refinery was brought back on-line following a shutdown for schduled maintenance.This was the first incident of this kind to occur at this facility. Analysis of the process data and eyewitness observations indicated that the dehydration tower, which was supposed to be maintained at a minimum of 100°C during the shutdown, was allowed to drift below 100°C for an unknown period of time. This deviation enabled liquid water to enter the storage tank. Three operational factors contributed to the accident. Corrective actions were recommended to prevent a recurrence of a similar incident.
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  • 40
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    Process Safety Progress 17 (1998), S. 184-189 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Dust explosions have been with us for a long time. The first record of a dust explosion occurred in Turin, Italy, on December 14, 1785 [1]. The detailed record of this event is left to us by Count Morozzo. The event took place in Mr. Giacomelli's bakery. We know from his account that the weather was unseasonably dry, that a boy who worked in the bakery was using a shovel to stir and transfer the flour to a chute from a store room to the bakery and he had a lighted lamp to work by. The rest, as the saying goes, is history. No one was killed, and the building was saved by the sagacious fact of having plenty of windows. Since that first record, of course, there have been many explosions with much loss of life and significant economic consequences.
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  • 41
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    Process Safety Progress 17 (1998), S. 190-195 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The RSST DIERS vent sizing methodology is revised to provide realistic design equations for reactive systems consistent with available large-scale experience. Using easy to obtain RSST data such as rate of temperature rise and rate of pressure rise excellent agreement is illustrated for hybrid, vapor and gassy reactive systems.
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  • 42
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    Process Safety Progress 17 (1998), S. 196-199 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: From the 1960s onwards, the chemical and oil industries developed and used a number of new safety techniques which, in time, became second nature to those who applied them. They included the use of QRA for deciding priorities, Hazop and audits for identifying problems, inherently safer design for avoiding hazards, and more thorough investigation of incidents for identifying underlying causes. However, it has not yet become second nature to remember the accidents of the past and the actions needed to prevent them happening again.I joined industry in 1944 and moved to production in 1952. Then, and for at least 15 years afterwards, safety was a non-technical subject that could be left to arts graduates and elderly foremen. There was concern that people should not be hurt - great attention was paid to the lost-time accident rate - but there was no realization, that it was a subject worthy of systematic study by experienced technologists.This view changed at the end of the 1960s. A new generation of plants had been built, operating at higher temperatures and pressures and containing larger inventories of hazardous chemicals; the result was a series of fires and explosions and a worsening fatal accident rate. Figure 1 shows the situation in ICI, at the time the UK, s largest chemical company. Other companies experienced a similar state of affairs.As a result in 1968, I was appointed one of the company's first technical safety advisers, an unusual appointment at the time for someone with my experience, and if the reason for my appointment had not been so obvious I would have wondered what I had done wrong. I and my colleagues tried to apply the same sort of systematic thinking to safety that we applied in our other professional work. We developed some new concepts and techniques and adopted others. A common feature of our ides, realized only in restrospect, was that they consisted of more than mere problem-solving techniques. Once people had got used to these new concepts and used them a few times, they began to look at a whole range of problems in a different way.
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  • 43
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    Process Safety Progress 17 (1998), S. W3 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 44
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    Process Safety Progress 17 (1998), S. 259-262 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Case histories of 65 incidents in runaway reactions and emergency relief in Taiwan were analyzed and classified into several categories according to their causes, materials involved, equipment types, reaction types, and ignition sources. The cases in reactors and storage tanks were examined in more detail owing to the higher probability or larger potential hazard in these two types of equipments. The most common consequence of the incidents are explosions, fires, and atmospheric release of toxic chemicals. The most severe case was a thermal explosion from an organic peroxide storage area which caused the death of 33 persons. Popping and direct releasing of process chemicals to the atmosphere from relieving devices cause the greatest environmental concerns to the community close to the plants. Runaway reactions in batch type reactors occur frequently due to various operational mistakes. Heat of reaction is the most frequent ignition source of runaway reactions and emergency relief.
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  • 45
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    Process Safety Progress 17 (1998), S. 272-277 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: EPA's Risk Management Program regulation, promulgated in June 1996 as 40 CFR Part 68 requires subject industries to submit Risk Management Plans by June 1999. This plan requires hazard assessment of the operations of a facility using worst case scenarios and alternative releases. EPA has provided an Off-site Consequence Analysis (OCA) guidance to help facilities in their hazard assessment.OxyChem will be significantly impacted by the RMP rule. This paper outlines OxyChem's general experience and its strategy in planning to comply with this rule. OxyChem's approach in the development of the scenarios required by the rule is described in this paper. Limitations involved in the use of EPA's look-up tables or a single modeling solution for conducting all of the OCA are discussed. A three tiered OCA approach is presented as a possible alternative.
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  • 46
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    Process Safety Progress 17 (1998), S. 209-212 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: HFC-227ea (CF3CHFCF3;1, 1, 1, 2, 3, 3, 3-heptafluoropropane) is an effective replacement for Halon 1301 in fire suppression systems, providing rapid extinguishment of flames through a combination of physical and chemical mechanisms. The vast majority of applications for HFC-227ea involve the protection of Class A hazards, which are characterized by low fuel loadings and low energy output, with fire sizes often in the range of 5-10 kW. Mid- and large-scale testing has demonstrated that HFC-227ea, at its minimum design concentration of 7.0% v/v, is effective at extinguishing fires typical of those expected to occur in electronic data processing (EDP) facilities, telecommunication facilities and anechoic chambers. The levels of HF produced following extinguishment of typical Class a fires with HFC-227ea were well below the estimated mammalian LC50 and the human Dangerous Toxic Load (DTL), and do not appear to present a threat to electronic equipment.
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  • 47
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    Process Safety Progress 17 (1998), S. 219-224 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Sandia National Laboratories (Sandia) has refined a process for developing inherently safer system designs based on methods used by Sandia to design detonation safety into nuclear weapons. The process was created when Sandia realized that standard engineering practices did not provide the level of safety assurance necessary for nuclear weapon operations, with their potential for catastrophic accidents. A systematic approach, which relies on mutually supportive design principles integrated through fundamental physical principles, was developed to ensure a predictably safe system response under a variety of operational and accident-based stesses. Robust, safe system designs result from this thematic approach to safety, minimizing the number of safety critical features. This safety assurance process has two profound benefits: the process avoids the need to understand or limit the ultimate intensity of off-normal environments and it avoids the requirement to analyze and test a large array of accident environment scenarios (e.g., directional threats, sequencing of environments, time races, etc) to demonstrate conformance to all safety requirements.
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  • 48
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    Process Safety Progress 17 (1998) 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 49
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    Process Safety Progress 17 (1998), S. 233-237 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new method is described to enhance the management of process safety risks such that the number and type of safety systems protecting against any hazard are consistently predicated upon risk. Further, that such an assignment of safety systems can be made consistent throughout an organization. This consistency is gained through standardization of qualitative risk ranking and by setting company guidelines.
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  • 50
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    Process Safety Progress 17 (1998), S. 243-258 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Research was carried out to develop improved protection guidelines for silane handling systems through enhanced understanding of the behavior of releases of this pyrophoric gas. The approach involved addressing three aspects of the problem: the prompt ignition behavior of silane; the reactivity characteristics of quiescent silane/air mixtures; and the rates of reaction of silane leaked into enclosures with and without explosion venting, in the presence of ventilation air flow. A first conclusion, reached from tests in a ventilated cabinet, was that, contrary to prevailing belief, the ventilation flow has no measurable effect on the prompt ignition of the release. From experiments in a 5.1-liter (311-in.3) sphere it was found that silane/air mixtures of concentrations between 1.4 and 4.1% (by volume) are explosive but stable. In this case, piloted ignition tests yielded laminar burning velocities up to 5 m/s (1000 ft/min). Mixtures between 4.5 and 38% (the maximum reached in the tests) were found to be metastable, and would undergo spontaneous ignition after a delay ranging from 15 to 120 seconds, with the shorter values corresponding to higher silane concentrations. Experiments were also performed in a 0.645-m3 (22.8-ft3) vessel both with and without explosion venting, to measure the rates of energy release associated with impulsively-started silane leaks from 1/8 and 1/4-in. (3.2 and 6.4-mm) lines. A method for the prediction of the venting requirements of partial-volume deflagrations (PVD) was evolved into a tool to quantify the pressure rise from ignition of silane leaks in enclosures. These results represent a significant step toward updating existing design recommendations which prescribe ventilation requirements that are based on outdated and, in some instances, misinterpreted data.
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    Process Safety Progress 17 (1998), S. 278-287 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gas explosion simulators are often used as tools in process plant design. This article presents some properties of gas explosions found using the EXSIM simulation software on three offshore modules with a total of nearly 10,000 simulations. The selected results are chosen for their supposed applicability to structural design in the process industries.Generalized data are presented for the effect of gas cloud size, explosion impulse vs. explosion pressure, pressure and impulse vs. duration, the probability of a “short” explosion, loading rate, pressure-time “shape” function, and the effect of introducing louvers.
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  • 52
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    International Journal for Numerical Methods in Engineering 18 (1982) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 41-66 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A system for describing three-dimensional surfaces in a form suitable for finite element analysis is described. The system makes extensive use of real-time interactive computer graphics techniques for both input and display. Discrete transfinite mappings are used as the mathematical basis for the surface representation. The mathematical basis and the reasons for choosing this form of representation are discussed. Explicit forms of the mappings based on Lagrange polynomial interpolation functions are presented. Finally, the interactive graphics procedures for defining finite element meshes are described.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 99-109 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Two highly accurate implicit Padé approximations to the transient heat conduction equation are investigated using the conjugate gradient method to solve, for the temperatures. The accuracy and stability of the approximations are discussed and numerical examples are presented showing the relative performance. Comparisons with the Crank-Nicolson method are also presented.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. i 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 195-210 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A clearer insight into the ‘shear locking’ phenomenon, which appears in the development of C0 continuous element using shear-flexible or penalty type formulations, is obtained by a careful study of the Timoshenko beam element. When a penalty type argument is used to degenerate thick elements to thin elements, the various approximations of the shear related energy terms act as different types of constraints and, depending on the formulation, two types of constraints which are classified as true or spurious may emerge. The spurious constraints, where they exist, are responsible for the ‘shear locking’ phenomenon, and its manifestation and elimination is demonstrated in a very simple example. The source of difficulty is shown to be the mathematical operations involved in the various shape function definitions and subsequent integration of functionals. It is seen that formulations that ensure only true constraints in the extreme penalty limit cases display far superior performance in the thick element situation as well, and thus guidelines for the development of efficient elements are drawn. A similar type of behaviour is observed in a shallow curved beam element and here ‘inplane locking’ can be eliminated by selective integration to obtain an improved curved beam element. However, ‘inplane locking’ does not cause a spurious constraint as the error quickly vanishes with the reduction of element size for a reasonable radius of curvature conforming with shallow shell theory.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 321-322 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 323-341 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The rate of convergence of the finite element method is a function of the strategy by which the number of degrees-of-freedom are increased. Alternative stragegies are examined in the light of recent theoretical results and computational experience.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 381-396 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Upwind finite element schemes remove spurious oscillations that occur in the solution of diffusion convection equations. Up to now these schemes lose part of their accuracy when the Peclet is large. As an improvement, it is proposed to move the integration nodes along the ‘streamlines’ before evaluating the elementary convection matrices. The displacements of the nodes along the streamlines, which are one-dimensional manifolds, are calculated analogously to well-known one-dimensional formulae. The last section of this paper illustrates this new method with the help of four examples which show its validity.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 314-320 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Quarter-point elements are used very frequently for fracture mechanics computations, because the quarter-point technique yields the required singular interpolation without any modification to existing software. This advantage is particularly significant for three-dimensional stress intensity factor computations because of the difficulty of implementing other techniques. However, in practical 3-D applications, the crack front is usually curved, and this note proves that a crack front distortion leads to a negative Jacobian in the region surrounding the crack front. The numerical difficulties to be expected depend on the aspect ratio of the elements.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 343-350 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The paper presents a smoothing technique to the oscillated contact pressure obtained by penalty methods for a class of unilateral contact problems in linear elasticity. The main result is to show that the smoothed contact pressure satisfies the so-called Babuska-Brezzi condition which dominates the convergence of the penalty method. One numerical example is described.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 435-444 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A method for the exploitation of screw translation symmetry for the vibration analysis of structures is presented. The method is capable of providing significant computational economies over the use of the lower axial translational symmetry of such structures.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 629-630 
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 632-634 
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  • 65
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 661-673 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Optimal structural desingn generally deals with frame or shell structures where the optimization is limited to resizing of structural members to obtain optimum cross-sections or thicknesses. Shape optimization solves another class of problems involving continuous structural components where the optimum shape (the shape of the boundaries and the surfaces of the components) is determined. This report describes shape optimization of three-dimensional structural components. The finite element method of analysis is used employing the 20-noded isoparametric element. The objective function, mass, is minimized by the direct use of nonlinear mathematical programming, specifically the feasible direction method. Numerical shape representation and the selection of design variables are the most important aspects of the problem. The problem is addressed from a practical standpoint and techniques are presented to minimize the number of desingn variables. Isoparametric representation of the surfaces and the numerical superposition of shapes are discussed. These techniques are compared and demonstrated on simple cantilever beams and their minimum mass designs are obtained. In one example, the optimum shape of a non-uniform cross-sectinal beam is obtained under stress constraint. The final design has a crosssectional shape varying over the length of the beam which could not be predicted using the bending theory of beams. One major difficulty encountered in some problems was that the shape changes during the optimization process may require a change in the finite element mesh because the initial configuration of the finite element mesh may result in very distorted elements for the new shape. The analyis with a mesh containing distorted elements may not be possible at all or the results of the analysis may be inaccurate.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 727-735 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Vector functions having a constant or zero divergence over a quadrilateral domain are derived using a parametric co-ordinate formulation. Expansion functions with a constant curl, defined over parallelograms and triangles, which can be used in moments-based investigations of electromagnetic wave interactions with surfaces and apertures, are then obtained. Finally, two basis functions, which have appeared in the literature and have been used to solve field problems associated with rectangular apertures and arbitrary surfaces, are identified as special cases of these expansion functions.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 927-944 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Finite element formulation for stress analysis of a twisting beam is developed. The formulation is effective for a prismatic beam with solid section as well as a thin-walled beam, and can be applied both to a pure-torsion problem and a warping-torsion problem. The formulation is of a great advantage to an elastic-plastic torsion problem. The formulation does not stand on the assumption of a thin-walled structure, and therefore torsional rigidity of the section can be evaluated exactly without using the so-called Saint-Venant's torsional constant. Torsional rigidity is, in this paper, evaluated directly by a warping function of the section. Warping function is evaluated numerically due to shape of the section, due to progress of plastic region and due to effect of finite displacement (finite rotation, small strain). Pure-torsion and warping-torsion of a rectangular beam and an H-beam, which have an elastic-plastic material property, are analysed, and the extension to the finite displacement problem is discussed. Many numerical examples are provided in order to check the accuracy of the formulation.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 955-957 
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 967-979 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A simple, efficient and economical numerical technique for the analysis of shallow shells-of arbitrary shape is presented. The technique is based upon the method of constant-deflection contours combined with the well-known finite element method. In the proposed method the elemental stiffness matrix is derived from a system of two consistent partial differential equations for two scalar functions using Galerkin's method. Several representative examples are included to indicate the effectiveness of the method.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 997-1017 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: An equation solver for the large unsymmetric systems of linear equations arising in the application of the boundary integral equation method to problems of linear elasticity in homogeneous or piecewise homogeneous solids is presented. The solver uses Gaussian elimination. The advantages of the solver over many existing eliminational or iterational methods are that it ignores many of the large groups of zeros that occur in piecewise homogeneous work, and also restrains growth of the number of non-zero matrix entries. Memory requirements and computation times therefore are reduced for many piecewise homogeneous problems.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 1055-1061 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Methods are described for forming element matrices for a wide variety of operators on tetrahedral finite elements, in a manner similar to that previously employed for line segments and triangles. This technique models the differentiation and product-embedding operators as rectangular matrices, and produces finite element matrices by replacing all required analytic operations by their finite matrix analogues. The method is illustrated by deriving the conventional matrix representation for Laplace's equation. Computer programs are available, which generate universal finite element matrices for use in various applications.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 1101-1103 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Ingraffea and Manu1 and Lynn and Ingraffea2 have shown that the size of the quarter-point elements can affect the computed elastic stress intensity factor. The nature of the effect is such that, all other details remaining constant, there is a particular crack tip element size which minimizes the error in the computed stress intensity factor. Here, size of element means the radial edge length. The reasons for this size dependence are discussed below. It will be seen that the discussion is in terms of the need to simultaneously represent the singular and finite stress terms in a given problem. The discussion has relevance to other formulations of crack tip elements.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 1115-1130 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: In a previous paper it has been proved by the author that the integral equations arising from the application of Green's formula to the Helmholtz equation in a limited domain can show a certain type of numerical instability, if a real Green's function is used. It has been also proved that such instabilities cannot arise if a complex Green's function is employed.However, it has been found in this latter case also that numerical instabilities can occur. This has been proved and thoroughly analysed for a circular domain, and a technique of avoiding these instabilities has been devised.Furthermore, when this technique is followed, very accurate results can be obtained, regardless of wavenumber used. Thus, only three or four segments are sufficient to describe a wavelength, contrary to what until now has been obtained, i.e. that at least six segments are always necessary. This last result has been shown to be valid also for geometries other than the circular one.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 1145-1151 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 1699-1717 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Dependence of dynamic response of nonlinear mechanical systems on design variables is analysed. An adjoint variable method is used to derive first- and second-order derivatives of measures of dynamic response with respect to design variables. A computational algorithm is presented for numerical calculation of first and second design derivatives. A simple oscillator example is solved analytically and by the adjoint variable method, with identical results. A burst fire automatic weapon mechanism with linear and nonlinear damping is treated numerically. It is shown that quadratic appriximations of dynamic response, using results of second-order design sensitivity analysis, can be substantially better than conventional linear approximations.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 1739-1739 
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    International Journal for Numerical Methods in Engineering 18 (1982) 
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 1745-1764 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Problems involving the diffusion and transport (angular dependence considered) of neutron radiation are frequently encountered in radiation physics and nuclear engineering. Neutron diffusion problems require substantial computer storage arising from the energy and spatial dependence, while in the case of transport problems the angular dependence of the neutron flux and of the neutron scattering process gives rise to a further considerable increase in storage. In the present work, a method has been developed which greatly eases the bandwidth problem in the solution of large systems of linear equations and algorithms have been developed to assemble and solve such systems of equations in one and two dimensions. The formalism used is the variational method and, for simplicity, linear interpolating functions have been used to derive a symmetric banded system of equations. Finite element algorithms have been implemented in the codes FEED1 and FEED2, which treat one and two space dimensions, respectively. Three benchmark problems are analysed in this paper and results are compared with finite difference discrete ordinate method solutions. It is shown that the finite element method provides fast and accurate solutions to neutron diffusion and transport problems.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 1829-1854 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A general and systematic discussion on the use of the operational method of Laplace transform for numerically solving complex time-dependent linear problems is presented. Application of Laplace transform with respect to time on the governing differential equations as well as the boundary and initial conditions of the problem reduces it to one independent of time, which is solved in the transform domain by any convenient numerical technique, such as the finite element method, the finite difference method or the boundary integral equation method. Finally, the time domain solution is obtained by a numerical inversion of the transformed solution. Eight existing methods of numerical inversion of the Laplace transform are systematically discussed with respect to their use, range of applicability, accuracy and computational efficiency on the basis of some framework vibration problems. Other applications of the Laplace transform method in conjunction with the finite element method or the boundary integral equation method in the areas of earthquake dynamic response of frameworks, thermaliy induced beam vibrations, forced vibrations of cylindrical shells, dynamic stress concentrations around holes in plates and viscoelastic stress analysis are also briefly described to demonstrate the generality and advantages of the method against other known methods.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 11-29 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The dispersive properties of finite element semidiscretizations of the two-dimensional wave equation are examined. Both bilinear quadrilateral elements and linear triangular elements are considered with diagonal and nondiagonal mass matrices in uniform meshes. It is shown that mass diagonalization and underintegration of the stiffness matrix of the quadrilateral element markedly increases dispersive errors. The dispersive properties of triangular meshes depends on the mesh layout; certain layouts introduce optical modes which amplify numerically induced oscillations and dispersive errors. Compared to the five-point Laplacian finite difference operator, rectangular finite element semidiscretizations with consistent mass matrices provide superior fidelity regardless of the wave direction.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 89-98 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Masters are defined as the degrees-of-freedom that are retained in the reduced eigenvalue problem. Various qualitative guidelines to select masters are published in the literature, but it is difficult to apply them to complex structures. In this paper a computational algorithm to select masters for complex structures is presented. This algorithm is based on a guideline14 which assures that the associated Guyan reduction process is valid. This algorithm eliminates one degree-of-freedom at a time satisfying the guideline, and preserves lower frequencies in the reduced eigenvalue problem. The algorithm presented in this paper is used to select masters for four different structural models. The natural frequencies of the associated reduced eigenvalue problems are calculated and compared with those calculated from the full eigenvalue problems.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 135-149 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A finite element model for symmetrically loaded shells of revolution is described. The nonlinear geometric effects are accounted for by incrementing loads and iterating for equilibrium. The iteration process also allows for nonlinear materials. The shell model accounts for large strains, large rotations and shear deformation. Three example problems demonstrate the ability of this model to solve linear problems. Also, three example problems demonstrate the versatility and accuracy of this model for nonlinear problems. These nonlinear example problems are an axially loaded cylinder and an internally pressurized spherical shell that have large membrane strains, and a cylinder that deforms into a spherical shape, having large rotations.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 166-166 
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 167-180 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The paper outlines a numerical procedure for the finite element solution of convective diffusion problems with significant convective terms using conventional (not upwinded) Galerkin methods in connection with ‘boundary-layer type’ elements. The underlying argument in the sequel is that the poor stability properties of conventional Galerkin methods are caused by the insufficient approximation of eigensolutions. These are located at some sections of the boundary and are only present within a generally very thin layer. Consequently, the identification of these layers and the satisfactory approximation of the eigensolutions are necessary and totally sufficient for a satisfactory solution. In the following we intend to present this procedure, its theoretical background and selected numerical results.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 245-257 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The solution of elastostatic bodies in frictionless contact is obtained by an automated direct method which exploits the theory of linear elasticity and circumvents the need for the inclusion of artificial interface elements, mathematical programming techniques or computation of contact pressure. The method is simple and economical to use and can be easily appended to existing numerical schemes such as the finite element method. The formulation and numerical algorithm are presented for body combinations which are independent of relative tangential displacements along the contact surface. The method is illustrated through an elementary example amenable to hand calculation. Numerical results for more realistic problems are given and compared to known solutions. It is concluded that the method provides a powerful means for both the analysis and design of contacting bodies when used in conjunction with a finite element computer program.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 291-309 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A finite element stress analysis capability for plane elasticity problems, employing the principle of stationary complementary energy, is developed. Two models are investigated. The first is a 24 d.o.f. rectangular finite element. The second model consists of an 18 d.o.f. triangular element. In order to allow for self-equilibrating stresses which are continuous within the element, the well-known Airy stress function ø is used. The function ø is represented by means of quintic Hermitian polynomials within the finite element. The values of the ø function and its derivatives up to order two are used as nodal parameters. For matching the stress function with the prescribed boundary tractions, additional equations are developed considering the force and moment equilibrium equations on the boundary consistent with the assumed stress function. These additional boundary equations are incorporated into the system equations using the Lagrangian multiplier technique. Excellent results are obtained for linear elastic problems even with coarse finite element discretization. Some examples of plane elasticity problems are solved and results compared.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 363-380 
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    Notes: The problem related to the derivation of conforming deep shell finite elements is examined in the light of the thin shell theory and using the classical Loves strain energy formulation. A family of quadrangular finite elements allowing for variable curvature is developed. It is shown how an exact conformity of the displacements can be ensured in a large number of cases.Various static and dynamic applications are used to illustrate the advantages of these elements.
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    International Journal for Numerical Methods in Engineering 18 (1982), S. 397-419 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The development of a geodesic beam finite element for use with a specific circular cylindrical shell finite element in the analysis of reinforced circular cylinders is described.The basic strain and curvature change equations are given and, from these, three versions of the geodesic beam element are developed. Two of the beams have nodal degress-of-freedom identical with the shell element. They differ in the treatment of the terms relating to rotation about the principal normal. The first version ignores this parameter but, under certain circumstances, the stiffness matrix contains terms which can contribute to the strain energy under arbitrary rigid body movement of the beam. This deficiency is removed by applying an aspect of Koiter's theory which is used to transform the curvature change equations.The introduction of additional rotational degress-of-freedom, at the end nodes of the beam element, produces a variation which is capable of accurately representing and transmitting in-surface bending effects to an adjoining beam element.Numerical evaluation successfully compares finite element solutions to basic problems for straight, circular and helical beams with theoretical strain energy solutions. Finally the beam is used in conjunction with a shell element to analyse an infinitely long circular cylinder, reinforced with equispaced rings, subjected to internal pressure.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 90
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 18 (1982) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 91
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 18 (1982), S. 521-533 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Finite element analysis of engineering structures commonly requires the use of inter-nodal displacement constraints. Current algorithms for this facility - elimination, Lagrange multipliers and penalty function methods - are briefly reviewed. An alternative approach is proposed which avoids some of the problems of these methods. This technique uses solution of the unconstrained stiffness equation with an extended number of right-hand sides. The resulting solutions are then combined to satisfy the constraints. This method has application in the synthesis of sub-structures with incompatible boundary variables. It is particularly efficient when the constraint affects many variables but the kinematics of the constraint can be expressed in terms of few independent variables, e.g. rigid body motion of part of the structure. In common with the Lagrange method, it produces data for use in a nonlinear analysis with constraints. The formulation of ‘rigid body’ constraints in geometric nonlinearity is detailed and demonstrated.
    Additional Material: 5 Ill.
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  • 92
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 18 (1982), S. 569-582 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: All physical process change with time and although physicists and engineers often freeze them to simplify their model studies, this is not always possible. Add to this the existence of several subregions within the modelling domain with different physical properties, the size and number of which change with time, and one has produced what might appear to be an intractable problem. Previous studies have shown that adaptive grids are an inconvenient way of modelling such moving interface problems and suggested that the use of a fixed grid with special discontinuous elements affords an efficient solution technique.This work presents and develops the characteristic matrices for two such elements, namely a quadratic triangle with an internal interface modelled by two straight lines and a quadratic isoparametric element. Both these elements are tested against an analytical solution to a simple Poisson equation. Such tests reveal the performance of the proposed elements to be satisfactory except for the definition of gradients near the interface.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 93
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 18 (1982), S. 591-607 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: To account for plastic deformation in plate and shell structures an elasto-viscoplastic solution algorithm is considered based on Perzyna's model for material behaviour. This algorithm can be employed to solve for time-dependent elasto-viscoplastic situations and by allowing steady-state conditions to be reached, elasto-plastic problems can also be considered.For the large displacement elasto-viscoplastic analysis of thin shells, an incremental stiffness procedure is employed together with a Lagrangian description of the stress and strain vectors. The Semiloof plate and shell elements are used for finite element space discretization.The procedures developed are applied to the solution of several numerical examples and the solutions compared with results from other sources where available.
    Additional Material: 13 Ill.
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  • 94
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 18 (1982) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 95
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 18 (1982), S. 675-685 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The position, size and surface temperature of circular holes inside a two-dimensional heat conductor are optimized to produce a minimum variation in surface temperature over a portion of the outer boundary. This problem, whic arises in thermal desing of moulds and dies, resembles those encountered in structural shape optimization because the internal geometry of the heat conductor depends on the design variables. In this paper, some of the traditional difficulties associated with shape optimization are overcome by analysing steady heat conduction with a special boundary integral method developed for two-dimensional regions with circular hole. This approach eliminates the need to regenerate a finite element mesh over the interior of the region each time the geometry is changed during the design process. It also increases the efficiency of the analysis by reducing the number of unknowns in the numerical discretization of the region. Since the objective function depends only on the boundary temperatures, there is no need to determine temperatures in the interior.The analysis method is applied to two problems arising in optimal thermal design of compression moulds. These examples show that the number of holes choson for the design strongly affects their resulting optimal arrangement as well as the ultimate uniformity of the cavity surface temperature.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 96
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 18 (1982), S. 755-764 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A triangular plate bending hybrid element is constructed according to Reissner's principle. It has 9 degrees-of-freedom and the shear effect is included. The C0 formulation of thick plate is directly developed to solve the thin plate by imposing the discrete Kirchhoff constraints. The matching problem for bending and shear in the hybrid model of thick plate is effectively treated by use of the principle of the energy regulation such that the unified analysis of thick and thin plates is realized. Finally, numerical examples are presented.
    Additional Material: 5 Ill.
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  • 97
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 18 (1982), S. 798-798 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 98
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 18 (1982), S. 798-798 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 99
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In this paper a triangular thin shell element is presented where C1 continuity is introduced by means of the penalty function technique. The displacement field has complete cubic polynomials for each component. The introduced constraint condition is the continuity of normal slopes of the transverse displacements along interelement boundaries. Classical thin shell theory for small deformations is applied. Several analyses of thin plates and shells are performed, including a large problem of practical interest, to study the effect of an increasing penalty factor. The accuracy of the results is estimated and compared to the actually occurred error. In the conclusions a recommended value for the penalty factor is given.
    Additional Material: 12 Ill.
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  • 100
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 18 (1982), S. 909-926 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: An interactive computer graphic system has been developed for generating and editing three-dimensional finite element meshes. The various difficulties inherent to the generation of solid three-dimensional geometries through an effective use of computer graphic techniques are examined to explain the advantages of this system. The method is a combination of discrete transfinite mapping and cubic spline blending algorithms, used, respectively, to create plane cross-sectional meshes, and to generate the three-dimensional geometry by interpolaring between the cross-sections. The communication between analyst and machine is based on a digitizing tablet and a refresh vector scope. The dynamic viewing capabilities and depth cueing of the vector display greatly enhance the perception of the mesh three-dimensionality. Multi-view dynamic display is also employed to facilitate node or element selection. The flexibility and usefulness of the system are illustrated with the help of three examples of practical interest.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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