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  • 2000-2004  (9)
  • 1960-1964  (4,471)
  • 1955-1959  (3,040)
  • 1890-1899  (2,182)
  • 1830-1839  (3,956)
  • Organic Chemistry  (11,896)
  • Chemical Engineering  (1,749)
  • genetic engineering
Material
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of technology and design education 10 (2000), S. 239-254 
    ISSN: 1573-1804
    Keywords: contexts ; critical reflection ; environment ; ethics ; genetic engineering ; impacts ; values
    Source: Springer Online Journal Archives 1860-2000
    Topics: Art History , Education , Technology
    Notes: Abstract Design and technology education aims to prepare young people for living in a rapidly changing technological society which will involve them in making many value judgements, some with complex ethical dimensions. Key aspects of the ethical judgements in relation to genetic engineering are examined: the hidden assumptions, the inevitable unpredictability when dealing with living processes highly interactive with the surroundings, the commercial and political pressures, and the underlying `world-views' and values. It is argued that responsible judgements therefore require wide consultation, sensitivity to social, cultural and moral issues, acknowledgement of the political and economic context, and above all, critical reflection on the beliefs and commitments that are shaping the vision and the drive. Teaching and learning strategies are needed that highlight the social and environmental context of technological activity, that encourage pupils to consider what determines the quality of their own lives and those of others, and that stimulates reflection on the values and beliefs which influence the priorities when value judgements are being made.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-6776
    Keywords: Escherichia coli ; genetic engineering ; metal-binding ; OmpC ; protein engineering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract The outer membrane protein, OmpC, from Escherichia coli was used to display metal-binding poly-histidine peptides on the surface of this bacterium. SDS-PAGE analysis of outer membrane protein preparations confirmed the expression of the metal-binding epitopes inserted in position 162 of the mature OmpC protein. Display of these epitopes was confirmed by epifluorescence microscopy of cells bound to Ni2+-NTA-agarose beads and metal adsorption experiments. The cells harboring one or two copies of the metal binding epitope were able to adsorb 3 to 6 times more Zn2+ (13.8 μmol g−1 cell), Fe3+ (35.3 μmol g−1 cell), and Ni2+ (9.9 μmol g−1 cell) metallic ions than control cells expressing the wild-type OmpC.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-6776
    Keywords: bioremediation ; genetic engineering ; heavy metal ; hydrogen sulfide ; thiosulfate reductase
    Source: Springer Online Journal Archives 1860-2000
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract The thiosulfate reductase gene (phsABC) from Salmonella typhimuriumwas expressed in Escherichia coliin order to produce sulfide from inorganic thiosulfate and precipitate metals as metal sulfide complexes. The sulfide-engineered strain removed significant amounts of heavy metals from the medium within 24 h: 99% of zinc up to 500 μM, 99% of lead up to 200 μM, 99% of 100 μM and 91% of 200 μM cadmium. In a mixture of 100 μM each of cadmium, lead, and zinc, the strain removed 99% of the total metals from solution within 10 h. Cadmium was removed first, lead second, and zinc last. These results have important implications for removal of metals from wastewater contaminated with several metals.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of agricultural and environmental ethics 12 (2000), S. 319-330 
    ISSN: 1573-322X
    Keywords: biotechnology ; consumer sovereignty ; genetic engineering ; informed consent ; product labeling ; risk communication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract Recently, both consumers and producers ofbiotechnology products have insisted thatcommunication between the two be improved. The formerdemand more democratic participation in the riskassessment process of biotechnology products. Thelatter seek to correct misinformation regardingalleged risks from these products. One way to resolvethese concerns, I argue, is through the use ofbiotechnology labels. Such labeling fosters consumerautonomy and moves toward more participatory decisionmaking, in addition to ensuring that informed consentfrom consumers is maintained. Furthermore, althoughvoluntary biotech-free labeling in lieu of biotechlabels may uphold consumer sovereignty, the latterremains a more effective strategy for achievingethical communication between consumers and producersof biotechnology products.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of agricultural and environmental ethics 12 (2000), S. 279-303 
    ISSN: 1573-322X
    Keywords: environment ; genetic engineering ; biotechnology ; pesticides ; agriculture ; pest control ; risks
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract Despite the application of 2.5 million tons ofpesticides worldwide, more than 40% of all potentialfood production is lost to insect, weed, and plantpathogen pests prior to harvest. After harvest, anadditional 20% of food is lost to another group ofpests. The use of pesticides for pest control resultsin an estimated 26 million human poisonings, with220,000 fatalities, annually worldwide. In the UnitedStates, the environmental and public health costs forthe recommended use of pesticides total approximately$9 billion/yr. Thus, there is a need for alternativenon-chemical pest controls, and genetic engineering(biotechnology) might help with this need. Diseaseand insect pest resistance to various pests has beenslowly bred into crops for the past 12,000 years;current techniques in biotechnology now offeropportunities to further and more rapidly improve thenon-chemical control of disease and insect pests ofcrops. However, relying on a single factor, like theBacillus thuringiensis toxin that has beeninserted into corn and a few other crops for insectcontrol, leads to various environmental problems,including insect resistance and, in some cases, athreat to beneficial biological control insects andendangered insect species. A major environmental andeconomic cost associated with genetic engineeringapplications in agriculture relates to the use ofherbicide resistant crops (HRC). In general, HRCtechnology results in increased herbicide use but noincrease in crop yields. The heavy use of herbicidesin HRC technology pollutes the environment and canlead to weed control costs for farmers that may be2-fold greater than standard weed control costs. Therefore, pest control with both pesticides andbiotechnology can be improved for effective, safe,economical pest control.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of agricultural and environmental ethics 13 (2000), S. 313-327 
    ISSN: 1573-322X
    Keywords: Agri-biotech companies ; agriculture ; biotechnology ; existing technologies ; farmers ; farm crisis ; genetic engineering ; hunger ; poverty ; productivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract The use of genetic engineering inagriculture has been the source of much debate. Todate, arguments have focused most strongly on thepotential human health risks, the flow of geneticmaterial to related species, and ecologicalconsequences. Little attention appears to have beengiven to a more fundamental concern, namely, who willbe the beneficiaries of this technology? Given the prevalence of chronic hunger and thestark economics of farming, it is arguable thatfarmers and the hungry should be the mainbeneficiaries of agricultural research. However, theapplication of genetic engineering appears unlikely tobenefit either of these two groups. This technology islargely controlled by the private sector, and itscontinued development hinges on its profitability.Thus, the only likely beneficiaries of the applicationof genetic engineering in agriculture are companieswith the capacity to use it.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of agricultural and environmental ethics 13 (2000), S. 43-51 
    ISSN: 1573-322X
    Keywords: genetic engineering ; inherent value ; moral obligation ; Swiss constitution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract The Swiss expert report suggests thatthe inherent dignity of a living being be identifiedwith its inherent value. But the phrase ``inherentvalue of a living being'' seems to connote two conceptsof inherent value. One has a morally obligatingcharacter but is counterintuitive because of itsegalitarianism. The other is one of non-moral value.It is more compatible with considered intuitions butinsufficient for substantiating the expert report'sclaim that human beings have moral duties towardsanimals and plants. The paper discusses theseconcepts. Consideration is then given to the problemof how discursive support can be generated for theexpert report's claim that human beings have the moralduty to abstain from impairing those functions andabilities of a non‐uman being that members of itsspecies as a rule can practice.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of agricultural and environmental ethics 13 (2000), S. 29-42 
    ISSN: 1573-322X
    Keywords: dignity of creatures ; genetic engineering ; human dignity ; inherent value ; Swiss Constitution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract In their report for the Swiss government onthe notion of the dignity of creatures, PhilippBalzer, Klaus-Peter Rippe, and Peter Schaber analyzethe relationship between human dignity and the dignityof creatures, taking them as two categoricallydifferent concepts. Human dignity is defined as the``moral right not to be humiliated,'' whereas thedignity of creatures is taken to be ``the inherentvalue of non‐human living beings.'' To my mind there isno need to draw a categorical distinction between thetwo concepts. Both notions could be brought togetherunder an all-encompassing concept of the inherentvalue of living beings, humans and non-humans alike,a concept one could name ``the dignity of livingbeings.'' Indeed, this very notion underlies theposition taken in the report, although this is notmade explicit by the authors themselves. As the aim of the paper is only to clarify theconcepts used, I do not go beyond this ``internal''critique of their position, i.e., I don't assess howthe claims articulated via these concepts – theclaim that humans and/or creatures have an inherentvalue consisting in a supposed intrinsic good – areto be justified, although I myself would be ratherskeptical that this might be successfully done.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of agricultural and environmental ethics 13 (2000), S. 7-27 
    ISSN: 1573-322X
    Keywords: dignity ; Swiss Constitution ; nonhuman inherent value ; genetic engineering
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract The 1992 incorporation of an article by referendum in the SwissConstitution mandating that the federal government issue regulations onthe use of genetic material that take into account the dignity ofnonhuman organism raises philosophical questions about how we shouldunderstand what is meant by ``the dignity of nonhuman animals,'' andabout what sort of moral demands arise from recognizing this dignitywith respect to their genetic engineering. The first step in determiningwhat is meant is to clarify the difference between dignity when appliedto humans and when applied to nonhumans. Several conceptions of humandignity should be rejected in favor of a fourth conception: the rightnot to be degraded. This right implies that those who have it have thecognitive capacities that are prerequisite for self-respect. In the caseof nonhuman organisms that lack this capacity, respecting their dignityrequires the recognition that their inherent value, which is tied totheir abilities to pursue their own good, be respected. This value isnot absolute, as it is in the case of humans, so it does not prohibitbreeding manipulations that make organisms more useful to humans. But itdoes restrict morally how sentient animals can be used. In regard togenetic engineering, this conception requires that animals be allowedthe uninhibited development of species specific functions, a positionshared by Holland and Attfield, as opposed to the Original Purposeconception proposed by Fox and the Integrity of the Genetic Make-upposition proposed by Rolston. The inherent value conception of dignity,as here defended, is what is meant in the Swiss Constitution article.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 11
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 135-135 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 5-10 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 16-25 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 35-38 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 67-67 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 79-82 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 106-110 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 110-114 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 19
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 130-131 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 20
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 274-275 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 21
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 277-281 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 22
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 91-97 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 23
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 293-297 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Constant pressure diffusion rates of hydrogen through Vycor porous glass were measured in nitrogen and neon systems. The experimental diffusivities are less than those predicted by the random pore model indicating that this model may not be satisfactory for a low porosity material such as Vycor. Interpreted in terms of an assembly of parallel pores the data suggest a tortuosity factor of approximately 2.4.Rate data for the ortho-para hydrogen reaction were also measured at -196°C. and 1 atm. The catalyst 2% nickel/Vycor was found to have pore properties (area, mean pore size, pore volume) similar to that of plain Vycor. Predicted effectiveness factors using the experimental diffusion data were in good agreement with values determined experimentally. The latter were evaluated from rate measurements on both pellet and particles (58 μ mean diameter).
    Additional Material: 3 Ill.
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  • 24
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 309-315 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A computational method has been developed for obtaining the solution to a class of optimization problems by the combined use of the maximum principle and a maximum (or minimum) seeking technique on the analogue computer. Various maximum seeking techniques can be used for this method. However if the random search technique is used, this computational method has the advantage of being able to investigate a large number of operating (or controlling) variables.The calculation procedure is essentially a trial-and-error procedure which is alternately integration and maximum seeking operations. The variables over which the system is to be optimized are approximated by a finite number of straight line segments n. Thus the maximum (or minimum) of the Hamiltonian function which is obtained by the maximum principle need only be obtained at n + 1 points along the optimization path (or trajectory).To illustrate the use of the method the optimum operating variable profiles (or gradients) in a tubular chemical reactor were computed.The present method, in addition to making it easier to investigate systems with a moderate number of state variables, can be used to solve problems with almost any kind of constraints and performance index encountered in ordinary optimum design problems. It offers some possibilities for on-line optimizing control of a process. A special purpose analogue computer could be built for this use.
    Additional Material: 8 Ill.
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  • 25
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 351-356 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 26
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 364-368 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
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  • 27
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 369-373 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
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  • 28
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 388-392 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 29
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 403-407 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 30
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 416-417 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 31
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 420-422 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 32
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 134-135 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 33
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 595-597 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 34
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 595-595 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 35
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 448-455 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The linearized equations of diffusion in a multicomponent system with flow and chemical reaction are shown to reduce to a set of equivalent binary diffusion equations.The concentrations and fluxes in a multicomponent system are described by linear combinations of appropriate solutions to the binary diffusion equation for steady and unsteady diffusion and convective mass transfer, laminar or turbulent.The rate of transfer of each component in a nonreacting n component system is a linear combination of the n-1 independent driving forces with proportionality constants which depend upon the multicomponent diffusion coefficients and appropriate binary mass transfer coefficients, while the concentration profile of each component is a linear combination of appropriate binary concentration profiles with proportionality constants which depend upon the multicomponent diffusion coefficients and the characteristic displacement from equilibrium of each component.The linearized theory is exact for small changes in concentration but needs further testing when the concentration changes and fluxes are large.
    Additional Material: 4 Ill.
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  • 36
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 475-482 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 12 Ill.
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  • 37
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 471-474 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The solutions of amines and water are in several respects among the most interesting that have been studied. They give some of the most perfect examples of lower consolute temperatures with fast breaking, almost flat solubility curves near the critical solution point. Their heat and entropy of solution are very high, and with few other solutions do the thermodynamic properties show greater sensitivity to molecular structure.The activity coefficients for these solutions are inordinately difficult to fit with equations such as the Margules, Redlich-Kister, etc., requiring as many as six constants. It has been found however that some of the properties can be correlated in terms of structural parameters which are measures of the steric and inductive contribution of the substituent groups. A very good correlation of the heat of solution at infinite dilution of amines in water is given. An equation of the Margules type employing orthogonal polynomials is given for which the constants are similarly correlated. Five six-carbon atom amines at 10°C. are included in the latter correlations, and the activity coefficients of all of these are represented in terms of two structural parameters.
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  • 38
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 509-517 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study was made of nucleate boiling bubble dynamics in saturated distilled water for various reduced gravity fields. The nucleation occurred on a very smooth horizontal nickel surface at low heat fluxes. Since because of the smooth surface finish only a few nucleation sites were active, it was possible to photograph individual bubbles that were not interfered with by adjacent bubble columns. Data were taken at seven different gravity fields in the range from 1.4 to 100% of earth gravity by placing the apparatus on a counterwieghted falling platform. Measurements were made of bubble departure diameters and frequencies, growth rates, contact angles, base circle diameters, and rise velocities. Comparisons were made to determine whether the measured gravity dependence of these quantities was in agreement with that predicted by correlations in the literature.
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  • 39
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    AIChE Journal 10 (1964), S. 517-523 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the absence of turbulent fluctuations the main effect of a velocity gradient on the floc properties is a rearrangement of particles within the floc producing a more dense floc structure. When the suspension is sufficiently dilute that floc-floc collisions are negligible, the limits on the floc diameter are (1 + α)5/3 〈 (Df/Dp) ≤ (1 + α)2, where α is the ratio of the volume of fluid immobilized in the floc structure to volume of solids in the floc structure as determined from hindred-settling measurements. These results set an upper limit on the floc size.Under turbulent flow conditions the principle mechanism leading to floc rupture is pressure differences on opposite sides of the floc which cause bulgy deformation and rupture. The breakup of the floc is resisted by the yield stress τy and is promoted by an increase in the energy dissipation per unit mass of fluid ∊. Because the energy dissipation per unit mass is at a maximum near the pipe wall, the floc size is at a minimum in this same region.By application of the concepts of local isotropy, the floc size is found to be proportional to (τy9/∊5)1/2once the turbulent intensity is sufficient to overcome the yield stress. In the wall region the floc diameter is proportional to (du/dr)3 (τy9/∊8)1/2.
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  • 40
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    AIChE Journal 10 (1964), S. 524-529 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The purpose of this study was to develop the use of semibatch operation of a recirculation reactor in kinetic studies. Ethylene hydrogenation over a supported copper catalyst was studied experimentally. In semibatch operation one of the reactants is fed at the rate necessary to hold the total pressure in the reactor constant. In ethvlene hydrogenation the reaction rate is directly equal to the feed rate, and the kinetics can be studied at constant partial pressure of either of the reactants. Since ethane is inert, this technique permitted the study of reaction rate as a function of one variable at a time.Although ethylene hydrogenation has been studied extensively, there is not general agreement regarding the kinetics over a copper catalyst. The results are themselves of interest because they indicate the reasons for the apparently conflicting data in the literature.
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  • 41
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    AIChE Journal 10 (1964), S. 548-550 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 42
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    AIChE Journal 10 (1964), S. 551-557 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: To test the importance of visco-elastic properties of non-Newtonian fluids in an oscillatory system of low frequency the dynamic characteristics of a series of non-Newtonian fluids were studied in oscillating manometers. The manometer fluid behavior was simulated on a digital computer by numerically integrating the axial component of the equation of motion. In the simulation cone and plate steady state rheological data were represented mathematically with the Sisko rheological model. Good agreement between simulation and experimental data was obtained. This agreement implies that steady state rheological models can be utilized in the description of unsteady state non-Newtonian systems where the characteristic period of the system is many times greater than the relaxation and retardation times of the fluid. When this characteristic period approaches these times, then rheological models which incorporate viscoelastic terms explicitly probably should be used.
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  • 43
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    AIChE Journal 10 (1964), S. 584-596 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 44
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    AIChE Journal 10 (1964), S. 584-600 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 45
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    AIChE Journal 10 (1964), S. 586-589 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 46
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    AIChE Journal 10 (1964), S. 274-274 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 47
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    AIChE Journal 10 (1964), S. 269-273 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is presented for solving the basic energy expression for the temperature distribution for turbulent heat transfer in a circular conduit with a digital computer. The method assumes a knowledge of the velocity distribution, the eddy conductivity term as a function of the radial position, and a constant wall temperature. For illustrative purposes only a dimensionless expression is derived from Reichardt's relationship which gives the eddy conductivity term as a function of radial position with Reynolds and Prandtl numbers as parameters.Incorporated in the computer program is Richardson's three-point extrapolation formula which permits the determination of a more accurate eigenvalue from three previously computed values which were obtained by using three different values of the reduced radial increment. Agreement with the Crank-Nicholson method is quite good, although the method with eigenvalues is considered to be superior. Eigenvalues determined from the analytical solution of the energy expression for the laminar flow case and those computed by the numerical method are in excellent agreement. This is indicative of the accuracy and reliability of the proposed numerical method.
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  • 48
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    AIChE Journal 10 (1964), S. 278-284 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Outline below is a method for simplification of the solution of diffusion problems involving irreversible first-order reactions. It permits writing the concentration profiles for reactive systems in terms of those for nonreactive systems of the same geometry and similar boundary conditions. The method is valid where fluid flow patterns and concentration boundary conditions are time independent and where the assumptions of constant density and mass diffusivity are acceptable. The useful results of this development are summarized in Equations (31) through (33) and represent a generalization of an earlier development by P. V. Danckwerts (1).
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  • 49
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    AIChE Journal 10 (1964), S. 652-655 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of reduction of ferrous oxide with hydrogen were studied in a 1½-in. diameter isothermal batch fluidized reactor. The effects of mass velocity and pressure on the reduction path were investigated over the ranges 5.3 to 19.2 moles/sq.ft.hr. and 1.3 to 5.4 atm. at 1,000° and 1,300°F. The results are correlated by means of instantaneous oxygen balances on the assumptions that there are no oxygen concentration gradients in the solid phase, that the distribution of residence times for the gas flow is represented closely by assuming complete mixing, and that the reduction rate is controlled at the oxide-metal interface. The rate of reduction increased with increasing pressure and mass velocity. An excellent correlation was obtained for the program at 1,000°F. At 1,300°F. sintering and grain growth of the product layer complicated the reduction process, and a correlation was not obtained. Application of the results to the design of commercial fluidized-reduction processes is discussed qualitatively.
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  • 50
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    AIChE Journal 10 (1964), S. 303-308 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Four different flow regimes may be identified during transport of dilute suspensions of solid particles through horizontal pipes by liquids in turbulent flow as the velocity is varied. The regimes may be characterized by the distribution of solids in the channel. In two of the regimes the bulk of the material is immediately adjacent to the bottom of the channel and is clumped up either into transverse waves (dunes or islands) with a reproducible periodicity or into longitudinal waves (long stria). The definition of the other two regimes is somewhat more arbitrary but may qualitatively be described as heterogeneous or homogeneous flow. Extensive studies of the conditions under which transverse and longitudinal waves occurred, when combined with results of previous studies, showed that all four of these flow regimes may be conveniently represented on a single diagram in which the terminal-settling velocity divided by the friction velocity and the Reynolds number on particle diameter and friction velocity are the coordinates. Because the particle Reynolds number based on the terminal-settling velocity can be uniquely defined as an additional parametre on such a diagram the particular flow behavior for any given combination of system and particle characteristics can be readily determined.
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    AIChE Journal 10 (1964), S. 339-344 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 52
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    AIChE Journal 10 (1964), S. 330-339 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Significant changes in heat and momentum transfer rates can be caused by finite interfacial velocities and external field forces. This study considers the nonlinear problem of combined free and forced convection in vertical and horizontal two-dimensional conduits with finite transverse velocity.Similarity transformations for the temperature function have been found which reduce the energy, momentum, continuity, and state equations for these configurations to nonlinear systems of two coupled ordianary differential euqations. These equations are solved by approximate methods to give Nusselt numbers and friction factors as well as velocity and temperature profiles.Stream to wall temperature differences increase with suction and decrease with injection. The effects of interfacial velocity on temperature profiles and heat transfer increase dramatically with Prandtl number. Because blowing and suction strongly affect temperature profiles they substantially modify natural convection effects in vertical flows. Suction creates steeper transverse temperature gradients and accentuates buoyancy effects in vertical flows. Conversely injection flattens temperature profiles and thus decreases the influence of buoyancy on the velocity field.
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    AIChE Journal 10 (1964), S. 373-379 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 10 (1964), S. 774-780 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 10 (1964), S. 398-402 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 10 (1964), S. 415-430 
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    AIChE Journal 10 (1964), S. 418-426 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 10 (1964), S. 430-430 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 10 (1964), S. 435-435 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 10 (1964), S. 804-809 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 10 (1964), S. 819-826 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 62
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    AIChE Journal 10 (1964), S. 836-842 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 63
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    AIChE Journal 10 (1964), S. 848-854 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The results of two investigations are reported. Air bubbles were formed at orifices submerged beneath each of fourteen liquids. The surface tension of the liquids varied from 17.8 to 72.4 dynes/cm., and the viscosities ranged from 0.436 to 713 centipoise. In the first investigation, air bubbles were formed at orifices at various angles of inclihation. Orifice diameters ranging from 0.159 to 0.396 cm. were employed. The air-flow rate was varied from 0.1 to 100 cc. (at standard conditions)/sec. The results were obtained with two different apparatuses by three independent investigators.In the second investigation, the effect of the velocity of a liquid flowing past a horizontal, submerged orifice on the formation of air bubbles was determined. Liquid velocities ranging from 0.34 to 2.5 cm/sec., which spanned the region of laminar flow, were employed. Orifice diameters ranged from 0.15875 to 0.3175 cm., air-flow rates from 0.5 to 100 cc/sec. (at standard conditions).It was found that the bubble formation observed in each of these investigations could be correlated with the physical variables of the system by the application of Newton's second law of motion to the bubble at the instant just prior to its release from the orifice.
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    AIChE Journal 10 (1964), S. 755-758 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 10 (1964), S. 483-486 
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    AIChE Journal 10 (1964), S. 775-783 
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    AIChE Journal 10 (1964), S. 776-792 
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  • 69
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    AIChE Journal 10 (1964), S. 817-819 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 10 (1964), S. 562-567 
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    AIChE Journal 10 (1964), S. 580-583 
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    AIChE Journal 10 (1964), S. 584-592 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 10 (1964), S. 597-597 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 10 (1964), S. 896-901 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Additional Material: 8 Ill.
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  • 76
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    AIChE Journal 10 (1964), S. 920-924 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 77
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    AIChE Journal 10 (1964), S. 913-919 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The calculus of variations, dynamic programing, and Pontryagin's maximum principle all are methods for optimzing serial decision processes, the kind associated with multistage operations having no recycle or bypass. Addition of recycle to a serial process makes it cyclic, and branching structures can be built up by connecting serial ones. The concept of cut state makes possible the decomposition of cyclic and branched systems into serial ones solvable by serial procedures. Under favorable circumstances cut states can be directed to their optimum values by efficient optimum seeking methods, which is not possible for ordinary state variables. These method are worthwhile only for loops having at least three stages, and the treatment of converging branches is more complicated than for diverging ones. Visualization of the various system structures is aided by functional diagrams. Definitions and nomenclature are developed for continued research on optimization of macrosystems by serial techniques.
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  • 78
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    AIChE Journal 10 (1964), S. 2-2 
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    AIChE Journal 10 (1964), S. 133-133 
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    AIChE Journal 10 (1964), S. 2-133 
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    AIChE Journal 10 (1964), S. 135-137 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 83
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 137-137 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 84
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 26-30 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 85
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 144-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 86
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 147-147 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 87
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 194-197 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 88
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 227-232 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 89
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 238-245 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 90
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 260-265 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The point of inversion of a water-in-oil type of dispersion to an oil-in-water type is investigated for several water-oil systems by studying the volume ratios of the phases in relation to their physical properties. The point of inversion for each system of an immiscible organic liquid and water and organic liquid mixture and water is obtained by varying the phase-volume ratios and determining the type of dispersion after complete mixing. The effects of temprature, interfacial tension, and density are found to have no correlation generally applicable to the systems studied. A volume-viscosity relationship is found to exist within limits. This correlation is that the phase-volume ratio at the point of inversion is equal to the square root of the ratio of teh viscosities of the respective phases at the interface. The theoretical aspects of this relationship are studied along with its limitations.
    Additional Material: 1 Ill.
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  • 91
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 130-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 92
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 155-159 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 93
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 180-186 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Unusual heat transfer phenomena have been observed between solid surfaces and fluids near their thermodynamic critical point. To understand better these phenomena temperature and velocity profiles and local heat transfer coefficients were measured for turbulent flow of carbon dioxide in a tube at 1,075 lb/sq. in. abs. (pc = 1,071). The results indicate a severe flattening of the radial temperature profiles, a maximum in the velocity profile between the wall and the tube axis, and a maximum in h' when the bulk fluid temperature passes through the transposed critical temperature.The results can be explained qualitatively by considering the variation with temperature of thermal conductivity near the tube wall and specific heat in the turbulent core.
    Additional Material: 13 Ill.
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  • 94
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 197-202 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 95
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 187-193 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Turbulent mixing of a dye solution injected at the center of a pipe was studied by means of a new light probe developed for the measurement of concentration fluctuations were made both along the axial distance and across the pipe. The concentration fluctuations persisted longer at the center-line region than anywhere else; this suggested the use of the decay of intensity at the center as an upper limit. Approximately 99% of the initial intensity decayed within 7.5 ft. (30 L/d). The concentration spectra along the axial distance indicated that the eddies initially undergo a scalar energy cascade. Because of the huge difference in the kinematic viscosity and molecular diffusivities the concentration spectra extend much farther toward high wave numbers than the velocity spectrum. Apparently a state of imbalance resulted between the supply of small eddies and their dissipation; this was marked by the appearance of a small hump in the spectra. The phenomenological approximations of Corrsin and of Beek and Miller could be used for the practical problem of predicting the decay of the intensity of the concentration fluctuations or mixing in the pipe geometry studied.
    Additional Material: 9 Ill.
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  • 96
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 202-205 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 97
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 206-213 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The adiabatic, evaporating, two-phase flow of steam and water in horizontal pipe including the critical flow was successfully described by a system of nonlinear differential equations which include different phase velocities, fluid acceleration, wall shear forces, interface shear forces, and mass and energy transfer between the phases. The solution of the differential equations by the method of Runge-Kutta was facilitated with a high-speed digital computer. Experimental data were obtained which included void fraction measurement by X-ray attenuation and showed that the theoretical equations described the complex flow phenomena to ± 10% when radial temperature gradients were small. Design charts based on the numerical solution of the theoretical equations are presented for rapid evaluation of the flow variables for the system steam-water including critical flow for inlet pressures from 30 to 150 lb./sq.in.abs., mass flow rates per unit area from 300 to 1,000 lb./sq. ft. sec., and L/D ratios from 25 to 1,000. The critical flow is defined as the maximum flow rate for a given pressure at the point of initial vaporization and L/D ratio.
    Additional Material: 7 Ill.
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  • 98
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 99
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 418-419 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 100
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 3-3 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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