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Nickel-Catalysed Reactions of Allyl Halides and Related Compounds (1967)

Chiusoli, G. P. ; Cassar, L.

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 6 (1967), S. 124-133

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ISSN: 0570-0833

Keywords: Allyl halides ; Catalysis ; Nickel ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Allyl compounds react with carbon monoxide, or with carbon monoxide and acetylene, in the presence of tetracarbonylnickel as catalyst. These catalysts are involved also in coupling reactions and addition reactions of activated olefins and ketones. Reactions of this type can be used for the preparation of unsaturated aliphatic acids, esters, nitriles, hydrocarbons, alicyclic ketones, keto acids, keto esters, diketones, lactones, phenols, and other compounds. The reactions proceed via π-allylnickel complexes.

Additional Material: 5 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/anie.196701241

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