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Synthesis of chlorobis/β-diketonato/oxotechnetium/V/ and tris/β-diketonato/technetium/III/ complexes (1989)

Hashimoto, K. ; Yamada, Y. ; Omori, T. ; [et al.]

Springer

Journal of radioanalytical and nuclear chemistry 135 (1989), S. 187-197

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ISSN: 1588-2780

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering

Notes: Abstract Chlorobis/β-diketonato/ oxotechnetium/V/ complexes [TcOCl/β-dik/2, β-diketone=acetylacetone, benzoylacetone and dibenzoylmethane] were newly synthesized using macroamount of99Tc. These complexes were further separated into geometrical isomers. Furthermore, an improvement of the yields for the syntheses of tris/β-dike-tonato/technetium/III/ complexes [Tc/β-dik/3, β-diketone=acetylacetone, benzoylacetone and 2-thenoyltrifluoroacetone] was examined using Tc/III/-thiourea complexes as a starting material.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02164971

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