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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 110 (1977), S. 3020-3025 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal and Molecular Structure of Bromobis(tert-butylisonitrile)dicarbonyl(phenylcarbyne)chromium and Bromodicarbonyl(phenylcarbyne)bis(triphenylphosphite)chromiumBy structure analyses of the title compounds 1 and 2 the influences of meridional substituents in carbyne complexes on the metal - carbyne carbon and the metal - halide bonds are investigated. Again extremely short chromium - carbon distances are observed for the organometallic triple bond in both complexes.
    Notes: Durch Strukturanalyse der Titelverbindungen 1 und 2 werden die Einflüsse meridionaler Substituenten in Carbin-Komplexen auf die Metall - Carbinkohlenstoff- und die Metall - Halogen-Bindungen untersucht. In beiden Komplexen werden wiederum extrem kurze Chrom - Kohlenstoff-Abstände für die metallorganische Dreifachbindung beobachtet.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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