ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
New Reagents, XXXVII. (α-Lithioalkyl)diphenylarsane Oxides: Synthesis and Application for the Indirect Nucleophilic HaloalkylationDue to ready accessibility and high nucleophilicity (α-lithioalkyl)diphenylarsane oxides (2) are favorable reagents for the synthesis of many organoarsenic compounds. In organic synthesis they are recommendable as reagents for indirect nucleophilic haloalkylation reactions (Hal=Cl, Br, I).
Notes:
(α-Lithioalkyl)diphenylarsanoxide (2) sind wegen ihrer bequemen Zugänglichkeit und hohen Nucleophilie günstige Reagenzien zur Darstellung zahlreicher Organoarsenverbindungen. In der organischen Synthese sind sie als Reagenzien für indirekte nucleophile Haloalkylierungen (Hal=Cl, Br, I) empfehlenswert.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19861190708