ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Note on the Reactivity of Silaethene Me2Si=C(SiMe3)2: conformative Effects in the Course of Diels-Alder Reactions with trans-and cis-Piperylene1)Silaethene Me2Si=C(SiMe3)2 reacts with trans-piperylene (which forms the cisoid conformation easier than cis-piperylene) to yield exclusively a [4+2] cycloadduct (3) in one step by a synchronous mechanism, with cis-piperylene only to a [2+2] cycloadduct (4) possibly by a two-step mechanism.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19871200923