ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
(Phthalocyaninato)cobalt(III) Adducts with Nitrogen Bases(Phthalocyaninato)cobalt dichloride, PcCoCl2, does not react with the nitrogenous bases L = pyridine (py), pyrazine (pyz), 2-methylpyrazine (mepyz), and 4,4′-bipyridine (bpy) to form phthalocyaninato complexes [PcCoL2]+ Cl- (1, X = Cl) containing Co3+ as the central metal atom. Instead the mixed complexes PcCo(L)Cl (3, X = Cl) are obtained exclusively, which are characterized by their IR, FIR, and UV/VIS spectra and their thermogravimetric (TG/DTA) data.
Notes:
(Phthalocyaninato)cobaltdichlorid, PcCoCl2, reagiert mit den Stickstoffbasen L = Pyridin (py), Pyrazin (pyz), 2-Methylpyrazin (mepyz) und 4,4′-Bipyridin (bpy) nicht zu Phthalocyaninato-Komplexen [PcCoL2]+ Cl- (1, X = Cl) mit Co3+ als Zentralatom. Es entstehen ausschließlich die gemischten Komplexe PcCo(L)Cl (3, X = Cl), die durch ihre IR-, FIR- und UV/VIS-Spektren und durch Thermogravimetrie (TG/DTA) charakterisiert werden.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19881210206
