ISSN:
0009-2940
Keywords:
Silaethene
;
Diels-Alder reaction
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
On the Reactivity of Silaethene Me2Si=C(SiMe3)2: Stereospecificity of Diels-Alder Reactions with Hexadienes1,2)[4 + 2] Cycloaddition of trans,trans;- and cis,trans;-2,4-hexadiene to silaethene Me2Si=C(SiMe3)2 (1) takes place stereo-specifically in one step with formation of 3 and 4, respectively. In addition, both reactions lead to ene products 5, 6.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240416