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Orbital Correspondence Analysis in Maximum Symmetry (1975)

Halevi, Emil Amitai

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 58 (1975), S. 2136-2151

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A method is described in which the ‘allowed’ course of a reaction is determined by means of an analysis - within the symmetry point group common to reactants and products - of their molecular orbitals and of the distortions that occur along the reaction path connecting them. The procedure, and its relation to and advantages over conventional correlation methods, is illustrated with a few very well known reactions: Cyclization of hexatriene, the ‘photochemical Diels-Alder reaction’ and the stepwise and concerted [2+2]-cycloadditions.

Additional Material: 9 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19750580726

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