ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The Influence of the Strain Energies on the Ionization and the Fragmentation of Tricyclo [5.2.1.02, 6]decanes, -decenes and -decadienesThe mass spectra of the title compounds are discussed. The inverse relationship of the abundance of the molecular ions with the calculated strain energies has been found to occur in the stereoisomers. The main fragmentation of the alkenes is the Retro-Diels-Alder cleavage. The stereochemical effects influence also the ionization and appearance energy.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19833250211