ISSN:
0021-8383
Schlagwort(e):
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The Influence of the Strain Energies on the Ionization and the Fragmentation of Tricyclo [5.2.1.02, 6]decanes, -decenes and -decadienesThe mass spectra of the title compounds are discussed. The inverse relationship of the abundance of the molecular ions with the calculated strain energies has been found to occur in the stereoisomers. The main fragmentation of the alkenes is the Retro-Diels-Alder cleavage. The stereochemical effects influence also the ionization and appearance energy.
Zusätzliches Material:
1 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/prac.19833250211