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Über die Pyrolyse von Pent-1-en-3,3-d2 (1983)

Kopinke, F.-D. ; Bach, G. ; Ondruschka, B. ; [et al.]

New York, NY : Wiley-Blackwell

Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 375-381

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ISSN: 0021-8383

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: On the Pyrolysis of Pent-1-ene-3,3-d2The distribution of deuterium in the main products of the thermal decomposition of pent-1-ene-3,3-d2 at 550 to 650°C was studied and interpreted. The results include conclusions on kinetic isotope effects, on relative reactivities of different C—H-bonds, and on the importance of nonterminal radical addition. It is shown that butadiene-d2 detected in the isotopically labeled butadiene fraction is a reliable target molecule for the homoallylic rearrangement of the pent-1-ene-4-yl-3,3-d2 radical.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/prac.19833250305

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