ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reaction of Bromo Derivatives of 6β-Bromocholest-4-en-3-one with NaBH4 and 13C-NMR Spectroscopic Characterization of the Reduction ProductsBromo derivatives of 6β-bromcholest-4-en-3-one (1a-f) were reduced with sodium borohydride. The main product of the reduction of 2α,6β-dibromcholest-4-en-3-one (1b) was 2α-bromocholesterol (2b). In other cases the corresponding derivatives of 6β-bromocholest-4-en-3β-ol (3a) were formed. The chemical shifts of all new products were determined. They confirmed the structure of these new compounds.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19863280418